Citation: ZHANG Fang-Wei, ZHOU Yan-Fang, DONG Jin-Qiao, LIU Bai-Zhan, ZHENG Sai-Jing, CUI Yong. Synthesis and Crystal Structure of a Novel Chiral 3D Metal-organic Framework Based on an N-methyl Substituted Salan Ligand[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1154-1158. shu

Synthesis and Crystal Structure of a Novel Chiral 3D Metal-organic Framework Based on an N-methyl Substituted Salan Ligand

a.
a. School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China;
b.
b. China Tobacco, Shanghai 200240, China

Received Date: 26 December 2013
Available Online: 11 February 2014
Fund Project:

A chiral 3D metal-organic framework [CdL]·DMSO·H₂O (1) was constructed by an N-methyl substituted salan ligand (H₂L), and characterized by elemental analyses, IR, TGA, powder XRD and single-crystal X-ray crystallography. 1 crystallizes in the chiral hexagonal space group P6₅22 with a=b=12.2175(3), c=51.450(3) Å, V=6650.9(4) Å³, Z=6, M_r=883.45, D_c=1.323 g·cm^-3, F(000)=2760, λ(CuKα)=1.54178 Å, μ=4.771 mm^-1, GOOF=1.041, R=0.0313 for 3901 observed reflections with I>2σ(I) and wR=0.0773. 1 consists of three identical sets of independent 3D frameworks interpenetrated with each other. In each set of such 3D frameworks, one half of the monomer (CdL)_1/2 as the building unit forms double antiparrel helical chains which are further bridged together by other (CdL)_1/2 units from adjacent helical chains. All CdL units in 1 adopt Δ geometry. DMSO and water guest molecules are found in the gap of the interpenetrated frameworks.
- metal-organic framework,
- chirality,
- metallosalan,
- crystal engineering
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