Citation: WANG Ji-Jiang, TANG Long, HOU Xiang-Yang, GAO Lou-Jun, FU Feng, ZHANG Mei-Li. Synthesis and Characterization of a New 2D Ca(Ⅱ) Coordination Polymer Containing 1D Calcium-oxygen Chains[J]. Chinese Journal of Structural Chemistry, ;2014, 33(7): 1069-1073. shu

Synthesis and Characterization of a New 2D Ca(Ⅱ) Coordination Polymer Containing 1D Calcium-oxygen Chains

1.
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an 716000, China

Corresponding author: WANG Ji-Jiang,
Received Date: 9 February 2014
Available Online: 9 June 2014
Fund Project: This project was supported by the National Natural Science Foundation of China (No. 21373178) (No. 21373178)the Natural Scientific Research Foundation of Shaanxi Provincial Education Office of China (No. 13JS124) (No. 13JS124)

A new 2D Ca(Ⅱ) coordination polymer, [Ca(H₂btc)(H₂O)₂]_n (1, H₄btc=biphenyl-3,3',5,5'-tetracarboxylic acid), has been synthesized using the hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analysis, IR, thermogravimetric analysis, and photoluminescent analysis. Complex 1 crystallizes in the monoclinic system, space group C2/c with a=17.5676(15), b=11.4496(8), c=7.6197(8) Å, β=102.787(2)°, V=1494.6(2) Å³, Z=4, D_c=1.797 Mg·m^-3, μ=0.483 mm^-1, F(000)=832, the final R=0.0348 and wR=0.0915 for 1521 observed reflections with I>2σ(I). Complex 1 has a 2D network containing 1D calcium-oxygen chains. These 2D networks are further connected by O-H…O hydrogen bonding interactions to generate a 3D supramolecular structure.
- coordination polymer,
- calcium-oxygen chains,
- photoluminescent property
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