Citation: WANG Rong-Ming, WANG Zhi-Ying, ZHANG Xiao-Wei, ZHANG Liang-Liang. Solvothermal Synthesis, Crystal Structure and Properties of a 3D Organically Amine Templated Lanthanide Sulfate[J]. Chinese Journal of Structural Chemistry, ;2014, 33(7): 1043-1049. shu

Solvothermal Synthesis, Crystal Structure and Properties of a 3D Organically Amine Templated Lanthanide Sulfate

1.
College of Science, China University of Petroleum (East China, Qingdao 266580, China

Received Date: 30 December 2013
Available Online: 24 February 2014
Fund Project: Supported by the NSFC (No. 21001115) (No. 21001115) the Fundamental Research Funds for the Central Universities (13CX02006A, 13CX05015A) (13CX02006A, 13CX05015A)

A new sulfate inorganic framework, {(C₂H₈N)₉[Nd₅(SO₄)₁₂]·2H₂O}_n (1) templated by organic amine, has been solvothermally synthesized and characterized by TGA, PXRD and single-crystal X-ray diffraction. Compound 1 crystalizes in monoclinic, space group C2/c with a=20.570(5), b=35.815(8), c=10.106(2) Å, C₁₈H₇₂N₉Nd₅O₅₀S₁₂, M_r=2315.73, V=6765(3) Å³, Z=4, D_c=2.274 g·cm^-3, μ=4.253 mm^-1, F(000)=4520, 2.52 < θ < 25°, λ(MoKα)=0.71073 Å, T=273(2) K, the final R=0.0401, wR=0.1022 and S=1.042. X-ray diffraction analysis reveals that complex 1 possesses a 3D inorganic sulfate framework with large 20-membered ring (20 MR) and 10-membered ring (10 MR) channels constructed by two kinds of SBUs. Moreover, the UV-vis and luminescent properties of complex 1 were also investigated.
- crystal structure,
- neodymium complex,
- inorganic framework,
- fluorescence
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