Citation: DING Dan-Dan, ZHANG Xiu-Mei, LIU Jie-Ping. Synthesis, Crystal Structure and Electrochemical Properties of a Cobalt Compound Based on N-(4-pyridylmethyl)imidazole Ligand[J]. Chinese Journal of Structural Chemistry, ;2014, 33(7): 1037-1042. shu

Synthesis, Crystal Structure and Electrochemical Properties of a Cobalt Compound Based on N-(4-pyridylmethyl)imidazole Ligand

1.
College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, China

Corresponding author: ZHANG Xiu-Mei,
Received Date: 25 December 2013
Available Online: 11 February 2014
Fund Project: Supported by the National Natural Science Foundation of China (21201069) (21201069)Natural Science Foundation of Anhui Province (1308085QB23) (1308085QB23)

One compound with N-(4-pyridylmethyl)imidazole liand, [Co(pyim)₂(N₃)₂]_n 1 (pyim=N-(4-pyridylmethyl)imidazole), was synthesized and structurally characterized. Compound 1 crystallizes in triclinic, space group P2₁/c with a=8.090(3), b=16.109(3), c=8.590(3), β=117.800(12)°, V=990.3(5) Å³, Z=2, M_r=461.37, D_c=1.547 g/cm³, F(000)=474, μ=0.901 mm^-1, the final R=0.0381 and wR=0.0950 for 1581 observed reflections with I>2σ(I). In this compound, the unique Co(Ⅱ) resides at a crystallographic inversion center and exhibits an octahedral coordination geometry. The adjacent Co(Ⅱ) ions are connected by the pyim ligands to form a 2D layer structure. The layers are stacked in an ABAB mode and reinforced by the weak interlayer C-H…N hydrogen bonds and π-π stacking to give a 3D architecture. The thermal property and electrochemical property of compound 1 have also been studied.
- cobalt compound,
- N-(4-pyridylmethyl)imidazole,
- crystal structure,
- electrochemical properties
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