Citation: ZHAO Zhen-Xin, MA Bu-Wei, REN Guo-Jian, ZHANG Ying-Hui. A New Terbium(Ⅲ) Coordination Compound with 2-Thiophenecarboxylic Ligand: Synthesis and Crystal Structure[J]. Chinese Journal of Structural Chemistry, ;2014, 33(7): 1013-1018. shu

A New Terbium(Ⅲ) Coordination Compound with 2-Thiophenecarboxylic Ligand: Synthesis and Crystal Structure

a.
a. College of Chemical and Materials Engineering, Henan University of Urban Construction, Pingdingshan, Henan 467036, China;
b.
b. College of Chemistry, Nankai University, Tianjin 300071, China

Received Date: 6 December 2013
Available Online: 6 June 2014
Fund Project: Supported by Henan Province Key Scientific Research Projects (122102210395) (122102210395)Pingdingshan Key Scientific Research Projects (No. 2013066) (No. 2013066)

A new coordination compound with formula [Tb(2-TC)₃(DMF)]_n (1, 2-TC=2-thiophenecarboxylic ligand and DMF=dimethylformamide) was synthesized by solvothermal method. The structure of compound 1 was determined by single-crystal X-ray diffraction analyses, and characterized by elemental analyses, IR and powder X-ray diffraction. Structure analysis reveals compound 1, exhibiting a one-dimensional chain structure, crystallizes in triclinic space group P2₁/c, with a=9.2751(19), b=16.490(3), c=15.865(5) Å, β=118.98(2)°, V=2122.7(9) Å³, D_c=1.916 g/cm³, M_r=612.45 (C₁₈H₁₅NO₇S₃Tb), F(000)=1196, μ(MoKα)=3.67 mm^-1, Z=4, R=0.0616 and wR=0.0962 for 3865 observed reflections (I>2σ(I)), and R=0.1092 for all data. Meanwhile, the photoluminescent properties of compound 1 were also investigated in the solid state at room temperature.
- 2-thiophenecarboxylic acid,
- terbium(Ⅲ),
- crystal structure
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