Citation: LIN Wei-Chen, GUO Wei-Gang, WANG Li-Hua, MA Xiu-Ling, XIANG Sheng-Chang, ZHANG Zhang-Jing. Synthesis, Crystal Structure and Characterization of a New Zinc Citrate Complex[J]. Chinese Journal of Structural Chemistry, ;2014, 33(4): 591-596. shu

Synthesis, Crystal Structure and Characterization of a New Zinc Citrate Complex

a.
a. College of Chemistry and Chemical Engineering, Fujian Provincial Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, China;
b.
b. College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China;
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c. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: ZHANG Zhang-Jing,
Received Date: 15 November 2013
Available Online: 18 February 2014
Fund Project:

A new Zn-citrate coordination complex {K[Zn(C₆H₅O₇)(H₂O)]}_n (1) was synthesi-zed via hydrothermal reaction. In the crystal structure of complex 1, each citrate serves as the quadricdentate ligand coordinating to three Zn(Ⅱ) ions, forming a zigzag chain, and such chains are further connected into a 3D network by the K⁺ linkers. Crystal data for complex 1: triclinic, space group P1, a=7.3487(9), b=7.5397(6), c=9.6772(8) Å, α=76.894(8), β=68.260(10), γ=65.155(10)°, V=450.34(7) Å³ and Z=2. Other characterizations by elemental analysis, IR, TG and fluorescence were also described.
- zinc citrate,
- synthesis,
- crystal structure,
- photoluminescence
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