Citation: Darkhijav B, SUO Quan-Ling, GAO Yuan-Yuan, HAI Er-Han, XIE Rui-Jun, ZHU Ning, HAN Li-Min. Synthesis and Crystal Structure of a Novel Ca(Ⅱ) Coordination Polymer Containing Dipyridine Dicarboxylic Ligand[J]. Chinese Journal of Structural Chemistry, ;2014, 33(4): 585-590. shu

Synthesis and Crystal Structure of a Novel Ca(Ⅱ) Coordination Polymer Containing Dipyridine Dicarboxylic Ligand

1.
Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, China

Corresponding author: HAN Li-Min,
Received Date: 29 September 2013
Available Online: 6 December 2013
Fund Project: Supported by the National Natural Science Foundation of China (NSFC 21266019, NSFC 21062011) (NSFC 21266019, NSFC 21062011) the Natural Science Fundation of Inner Mongolia (20080404MS020) (20080404MS020)Program for New Century Excellent Talents in University (NCET-08-858) (NCET-08-858)

The novel alkaline metal complex Ca(BPDCH)₂ (1, BPDCH₂=2,2'-bipyri-dine-5,5'-dicarboxylic acid) has been synthesized by the hydrothermal reaction of Ca(NO₃)₂·4H₂O with 2,2'-bipyridine-5,5'-dicarboxylic acid. The molecular and crystal structures of complex 1 have firstly been characterized by FTIR, elemental analysis, and X-ray single-crystal diffraction. The 3D MOF structure of complex 1 was interpreted by the versatile binding modes-the intermolecular hydrogen bonds and π-π stacking interactions of 2,2'-bipyridine-5,5'-dicarboxylic acid ligand. The analysis results show complex 1 belongs to a coordination polymer with 3D MOF structure. The results of thermogravimetric analysis and solubility demonstrate complex 1 is a thermostable compound and does not dissolve in water and traditional organic solvents.
- calcium complex,
- coordination polymer,
- molecular and crystal structure,
- bipyridine-dicarboxylic ligand,
- thermo-stability
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