Citation: HU Jin-Song, ZHANG Lei, SHI Jian-Jun, XING Hong-Long, HE Jie. Construction of a 3D Co(Ⅱ) Framework Based on Two Types of V-shaped Bidentate Ligands[J]. Chinese Journal of Structural Chemistry, ;2014, 33(4): 579-584. shu

Construction of a 3D Co(Ⅱ) Framework Based on Two Types of V-shaped Bidentate Ligands

HU Jin-Song ^a,b,, ,
ZHANG Lei ^a ,
SHI Jian-Jun ^a ,
XING Hong-Long ^a ,
HE Jie ^a

a.
a. School of Chemical Engineering, School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001, China;
b.
b. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: HU Jin-Song,
Received Date: 22 September 2013
Available Online: 13 December 2013
Fund Project: This work was supported by the National Natural Science Foundation of China (21301005, 21271008, 51173002) (21301005, 21271008, 51173002) Natural Science Foundation of Anhui Province (1308085QB34) (1308085QB34)

A three-dimensional (3D) coordination polymer {[Co(bdc)(dpb)]·H₂O}_n (1) was prepared by solvothermal reaction of 1,3-dipyridyl benzene (dpb) with deprotonated 1,3-benzene-dicarboxylate (H₂bdc), and was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It crystallizes in the monoclinic system, space group C2/c with a=15.478(6), b=12.865(5), c=24.091(10) Å, β=95.599(5)°, V=4774(3) Å³, C₂₄H₁₈CoN₂O₅, M_r=473.34, D_c=1.267 g/cm³, F(000)=1864.0, μ=0.748 mm^-1 and Z=8. Each Co(Ⅱ) ion links three bdc^2- anions to form an infinitely 1D ladder-shaped chain containing binuclear [(COO)Co]₂ cluster, and dpb links adjacent 1D chains to form a 3D pcu framework. In addition, the UV-vis of 1 was also studied.
- coordination polymer,
- V-shaped ligand,
- crystal structure,
- UV-vis spectrum
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