Citation: Jing-ping Wang, Zheng-hao Fei. ADSORPTION CHARACTERISTICS OF CHLOROPHENOLS FROM AQUATIC SYSTEMS BY HYPERCROSSLINKED RESINS MODIFIED WITH BENZOYL GROUP[J]. Chinese Journal of Polymer Science, ;2006, 24(5): 545-551. shu

ADSORPTION CHARACTERISTICS OF CHLOROPHENOLS FROM AQUATIC SYSTEMS BY HYPERCROSSLINKED RESINS MODIFIED WITH BENZOYL GROUP

  • Received Date: 19 December 2005
    Revised Date: 16 February 2006

  • Ahypercrosslinkedpolymericadsorbent(ZH-03)foradsorbingandremovingchlorophenoliccompoundsfromtheiraqueoussolutionswasstudied,includingthestaticadsorption.TheequilibriumadsorptiondatawerefittoFreundlichadsorptionisothermicmodelstoevaluatethemodelparameters.ThermodynamicstudiesontheadsorptionofchlorophenoliccompoundsonZH-03indicatedthattherewerechemisorptiontransitionsfor2,4,6-trichlorophenolandphysicaladsorptionprocessesfor2-chlorophenoland2,6-chlorophenol,andZH-03showedthehomogeneousnatureoftheadsorbentsurface.ColumnadsorptionforchlorophenolswastewatershowstheadvantagesoftheZH-03adsorbentforadsorbingthefollowingchlorophenoliccompoundsas2-chlorophenol,2,6-dichlorophenoland2,4,6-trichlorophenol.SodiumhydroxidewasusedfordesorptingchlorophenolsfromZH-03andshowedexcellentperformance.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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