Citation: Jing Jiang LIU, Gua Lin DUAN, Xiao Tian Liang. AN AB INITIO STU DY ON THE CORELATION BETWEEN THE ABSOLUTE CONFIGURATION AND THE CD SPECTRA OF ORGANIC PEROXIDES[J]. Chinese Chemical Letters, ;1991, 2(3): 245-248. shu

AN AB INITIO STU DY ON THE CORELATION BETWEEN THE ABSOLUTE CONFIGURATION AND THE CD SPECTRA OF ORGANIC PEROXIDES

a Chemistry Dept., Nankai Univ., Tianjin 300071;
b Institute of Materia Medica, Beijing 100050

Received Date: 17 October 1990

Correlation between the absolute configuration and the CD spectra of organic peroxides was studied by ab initio method with a mo-del moleeule CH₃-O-O-CH₃. For P form when 0° ≤θ (twist angle of C-O-O-C) <90°, there is positive Cotton effect;when 90°< θ ≤180°, there is negative Cotton effect;the curve is bisignate at θ=90°.
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