Citation: Chun Juan LIU, Li Hua LIU, Shi Yan YANG, Wei GAO, Ze Min XIE. A Novel Method to Synthesize Polyorganozircosilazane[J]. Chinese Chemical Letters, ;2002, 13(12): 1225-1226.
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A new kind of polyorganozircosilazane as Si/Zr/C/N-based ceramic precursor was synthesized from the condensation reaction of hexamethylcyclotrisilazane lithium salts (D3NLi) and zirconium tetrachloride (ZrCl4). In the presence of N, N, N', N'-tetramethyl ethylene diamine (TMEDA), polyorganozircosilazane was obtained in high yield.
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