Citation: Xin Hua XU, Xian HUANG. Reduction of Diaryldiselenides by System of Cp₂TiCl₂/BuⁱMgBr/THF and Its Application in Synthesis of Unsymmetrical Diaryl Selenides[J]. Chinese Chemical Letters, ;2000, 11(6): 473-474. shu

Reduction of Diaryldiselenides by System of Cp₂TiCl₂/BuⁱMgBr/THF and Its Application in Synthesis of Unsymmetrical Diaryl Selenides

Xin Hua XU ^a ,
Xian HUANG ^b

a Institute of Elemento-Organic Chemistry, Nankai University Tianjin 300071;
b Department of Chemistry, Zhejiang University, Xi Xi Campus, Hangzhou 310028

Received Date: 28 December 1999
Revised Date: 14 March 2000

Reduction of diaryldiselenides by the system of Cp₂TiCl₂/BuⁱMgBr/THF gave the nucleophilic arylselenium complex. They reacted with diaryl iodonium salts to afford unsymmetrical diaryl selenides in high yields.
- Diaryl selenides,
- reduction,
- titanocene dichloride,
- isobutylmagnesium bromide,
- arylselenium complex of titanocene,
- diaryl iodonium salts,
- unsymmetrical diaryl selenides
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