Citation: Wei Ma, Mei Meng, Xue Jiang, Bing-Tao Tang, Shu-Fen Zhang. Synthesis of a water-soluble macromolecular light stabilizer containing hindered amine structures[J]. Chinese Chemical Letters, ;2013, 24(2): 153-155. shu

Synthesis of a water-soluble macromolecular light stabilizer containing hindered amine structures

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China

Corresponding author: Wei Ma, Shu-Fen Zhang,
Received Date: 26 September 2012
Available Online: 1 January 2013
Fund Project: The authors gratefully thank the financial support of the National Natural Science Foundation of China (Nos. 20806013, 20923006) (Nos. 20806013, 20923006)the National Key Technology R&D Program (No. 2011BAE07B08). (No. 2011BAE07B08)

A novel water-soluble macromolecular light stabilizer was synthesized by grafting 2-chloro-4,6-bis-[(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazine onto polyvinylamine. The intermediate 2-chloro-4,6-bis-[(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazine and the obtained macromolecular light stabilizer were characterized by ¹H NMR, HRMS, IR and UV spectroscopy. Cotton fabrics dyed with C.I. Reactive Yellow 145, C.I. Reactive Red 195 and C.I. Reactive Blue 19 were finished with the macromolecular light stabilizer, and the lightfastness of the dyes was tested. The results showed that the lightfastness of the reactive dyes was improved by 0.5-1.0 grade after being finished and the macromolecular light stabilizer exhibited good wash fastness and thermal stability.
- Water-soluble macromolecular light,
- stabilizer,
- Hindered amine,
- Lightfastness of reactive dyes,
- Finishing
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沈阳化工大学材料科学与工程学院沈阳 110142