Citation: Jie Wang, Ze-Xing Wu, Li-Li Han, Yuan-Yang Liu, Jun-Po Guo, Huolin L. Xin, De-Li Wang. Rational design of three-dimensional nitrogen and phosphorus co-doped graphene nanoribbons/CNTs composite for the oxygen reduction[J]. Chinese Chemical Letters, ;2016, 27(4): 597-601. shu

Rational design of three-dimensional nitrogen and phosphorus co-doped graphene nanoribbons/CNTs composite for the oxygen reduction

a Key Laboratory of Material Chemistry for Energy Conversion and Storage(Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;
b Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, Brookhaven, NY 11973, USA;
c School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China

Received Date: 14 December 2015
Revised Date: 30 December 2015

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 21306060, 21573083), the Program for New Century Excellent Talents in University of Ministry of Education of China (No. NCET-13-0237), the Doctoral Fund of Ministry of Education of China (No. 20130142120039), the Fundamental Research Funds for the Central University (Nos. 2013TS136, 2014YQ009). We thank Analytical and Testing Center of Huazhong University of Science and Technology for allowing us to use its facilities. S/TEM work was carried out at the Center for Functional Nanomaterials, Brookhaven National Laboratory, which is supported by the U.S. Department of Energy, Office of Basic Energy Sciences (No. DE-SC0012704).

In the present work, we report nitrogen and phosphorus co-doped 3-D structured carbon nanotube intercalated graphene nanoribbon composite. The graphene nanoribbons are prepared via partial exfoliation of multi-walled carbon nanotubes. In the graphene nanoribbons/CNTs composite, carbon nanotubes play a role of skeleton and support the exfoliated graphene nanoribbons to form the stereo structure. After high temperature heat-treatment with ammonium dihydrogen phosphate, the unique structure reserves both the properties of carbon nanotube and graphene, exhibiting excellent catalytic performance for the ORR with excellent onset and half-wave potential, which is similar to commercial Pt/C electrocatalysts.
- Graphene nanoribbons,
- Carbon nanotube,
- Doping,
- Electrocatalyst,
- Oxygen reduction reaction
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