Citation: Min LI, Bin XU, Hua CHEN, Hong Jie ZHENG, Xue Yuan HUANG, Yao Zhong LI, Xian Jun LI. Biphasic Catalytic (Hydroformylation of 1-Dodecene in Micellar System with Cationic Gemini Surfactants[J]. Chinese Chemical Letters, ;2004, 15(9): 1022-1024. shu

Biphasic Catalytic (Hydroformylation of 1-Dodecene in Micellar System with Cationic Gemini Surfactants

Department of Chemistry, Sichuan University, Chengdu 610064

Received Date: 24 July 2003

Fund Project: We thank the State Key Basic Program of China (G2000048008) for the financial support.

The promotion effect of cationic gemini surfactants for the hydroformylation of 1-dodecene in the organic/aqueous biphasic catalytic system is reported. The hydroformylation reaction in the presence of gemini surfactant occurred with higher turnover frequency and higher selectivity for linear aldehyde than using conventional monomeric surfactant CTAB.
- Hydroformylation,
- gemini surfactant,
- 1-dodecene,
- rhodium catalyst
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