Citation: He Xiaoyan, Wang Meng, Zhang Caiyun, Qiang Shenglu. Research on the Catalysts of Polymer Supported Metal Nanoparticles with Core-Shell Structure[J]. Chemistry, ;2016, 79(12): 1113-1120. shu

Research on the Catalysts of Polymer Supported Metal Nanoparticles with Core-Shell Structure

1.
College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received Date: 1 June 2016
Available Online: 16 August 2016
Fund Project:

Polymer-supported catalysts with core-shell structure have attracted great attention in the area of catalytic chemistry because of the unique structure, morphology and properties of the supporting materials. This article reviews the preparation and corresponding catalytic performance of the catalysts of polymer supported metal nanoparticles with core-shell structure, which comprise spherical polymer brushes supported metal nanoparticles, polymer hollow microspheres loaded with metal nanoparticles, polymer solid microspheres coating with metal nanoparticles. The influence of the composition and the structure characteristics of support materials on the catalytic activity and stability of the catalysts are illustrated. Finally the advantages and short-comings of such catalytic materials are summarized, in addition, the prospect of performance and applications are also forecasted.
- Core-shell structure,
- Polymer-supported materials,
- Metal nanoparticles,
- Catalytic chemistry
1. [1]
  [1] N Sahiner, O Ozay, E Inger et al. J. Power Sources, 2011, 196(23): 10105~10111.
2. [2]
  [2] Y Ma, Y Ni, F Guo et al. Cryst. Growth Des., 2015, 15(5): 2243~2252.
3. [3]
  [3] T M Baber, D Graiver, C T Lira et al. Biomacromolecules, 2005, 6(3): 1334~1344.
4. [4]
  [4] J Heveling. J. Chem. Educ., 2012, 89(12): 1530~1536
5. [5]
  [5] P V Kamat, N M Dimitrijevi. Sol. Energy, 1990, 44:2(2):83~98.
6. [6]
  [6] P Ball, L Amp, L Garwin. Nature, 1992, 355(6363):761~766.
7. [7]
  [7] 郭玉明, 王玲玲, 张洁等. 化学通报, 2011, 74(2):106~115.
8. [8]
  [8] K An, G A Somorjai. ChemCatChem, 2012, 4(10): 1512~1524.
9. [9]
  [9] H H Zhou, Y L Li, J Q Huang et al. T. Nonferr. Metal. Soc., 2015, 25(12): 4001~4007.
10. [10]
  [10] D Varade, K Haraguchi. Chem. Commun., 2014, 50(23): 3014~3017.
11. [11]
  [11] H Liu, D Wan, J Du et al. ACS Appl. Mater. Interf., 2015, 7(37): 20885~20892.
12. [12]
  [12] M Schwarze, J Keilitz, S Nowag et al. Langmuir, 2011, 27(10): 6511~6518.
13. [13]
  [13] F Wen, W Zhang, G Wei et al. Chem. Mater., 2008, 20(6): 2144~2150.
14. [14]
  [14] Q An, Z Li, R Graff et al. ACS Appl. Mater. Interf., 2015, 7(8): 4969~4978.
15. [15]
  [15] J Zhang, S Xu, E Kumacheva. Adv. Mater., 2005, 17(19): 2336~2340.
16. [16]
  [16] J Yuan, S Wunder, F Warmuth et al. Polymer, 2012, 53(1): 43~49.
17. [17]
  [17] J Han, S Lu, C Jin et al. J. Mater. Chem. A, 2014, 2(32): 13016~13023.
18. [18]
  [18] Y Mei, Y Lu, F Polzer et al. Chem. Mater., 2007, 19(5): 1062~1069.
19. [19]
  [19] T Yao, Q Zuo, H Wang et al. J. Colloid Interf. Sci., 2015, 450:366~373.
20. [20]
  [20] J Yu, W C Guo, M Yang et al. Sci. China Chem., 2014, 57(9):1211~1217.
21. [21]
  [21] B Samanta, X C Yang, Y Ofir et al. Angew. Chem. Int. Ed., 2009, 48(29): 5341~5344.
22. [22]
  [22] J Han, Y Liu, R Guo. Adv. Funct. Mater., 2009, 19(7): 1112~1117.
23. [23]
  [23] A Katakai, N Seko, T Kawakami. J. At. Energy Soc. Jpn., 1998, 40(11):878~880.
24. [24]
  [24] K Min, S Kiyohara, S Konishi et al. J. Membrane Sci., 1996, 117(1-2):33~38.
25. [25]
  [25] S Wang, M Zhang, L Zhong et al. J. Mol. Catal. A-Chem., 2010, 327(1-2):92~100.
26. [26]
  [26] D Li, B Zhao. Langmuir, 2007, 23(4): 2208~2217.
27. [27]
  [27] S Tsuji, H Kawaguchi. Macromolecules, 2006, 39(13):4338~4344.
28. [28]
  [28] J N Kizhakkedathu, R Norris-Jones, D E Brooks et al. Macromolecules, 2004, 37(3):734~743.
29. [29]
  [29] X Chen, D P Randall, C Perruchot et al. Colloid Interf. Sci., 2003, 257(1):56~64.
30. [30]
  [30] X He, Z Liu, F Fan et al. J. Nanopart. Res., 2015, 17(2):1~10.
31. [31]
  [31] L Yan, M Yu, R Walker et al. Polymer, 2006, 47(14):4985~4995.
32. [32]
  [32] N Pradhan, A Pal, T Pal. Colloid Surf. A, 2002, 196(2~3):247~257.
33. [33]
  [33] Y Lu, J Yuan, F Polzer et al. ACS Nano, 2010, 4(12):7078~7086.
34. [34]
  [34] B Liu, D Zhang, J Wang et al. J. Phys. Chem. C, 2013, 117(12):6363~6372.
35. [35]
  [35] A Dong, Y Wang, D Wang et al. Micropor. Mesopor. Mat., 2003, 64(1-3):69~81.
36. [36]
  [36] F Caruso. Chem. Eur. J., 2000, 6(3):413~419.
37. [37]
  [37] E Donath, G B Sukhorukov, F Caruso et al. Angew. Chem. Int. Ed., 1998, 37(16): 2201~2205.
38. [38]
  [38] A Graff, M Winterhalter, W Meier. Langmuir, 2001, 17(3):919~923.
39. [39]
  [39] S J Ding, C L Zhang, M Yang et al. Polymer, 2006, 47(25): 8360~8366.
40. [40]
  [40] Y Li, X Li, Y Li et al. Angew. Chem. Int. Ed., 2006, 45(22): 3639~3643.
41. [41]
  [41] G H Ma, S Omi, V L Dimonie et al. J. Appl. Polym. Sci., 2002, 85(7):1530~1543.
42. [42]
  [42] F Caruso. Adv. Mater., 2001, 13(1):11~22.
43. [43]
  [43] A A Antipov, G B Sukhorukov, E Donath et al. J. Phys. Chem. B, 2001, 105(12):2281~2284.
44. [44]
  [44] P Liu. E-Polymers, 2013, 7(1):725~755.
45. [45]
  [45] S Miao, C Zhang, Z Liu et al. J. Phys. Chem. C, 2008, 112(3):774~780.
46. [46]
  [46] 何晓燕, 刘志荣, 范富红等. 应用化学, 2015, 32(3):310~316.
47. [47]
  [47] Y Lan, L Yang, M Zhang et al. ACS Appl. Mater. Interf., 2010, 2(1):127~133.
48. [48]
  [48] T Yao, T Cui, H Wang et al. Nanoscale, 2014, 6(13):7666~7674.
49. [49]
  [49] L Kong, X Lu, E Jin et al. J. Solid State Chem., 2009, 182(8):2081~2087.
50. [50]
  [50] M Álvarez-Paino, G Marcelo, A Muñoz-Bonilla et al. Macromolecules, 2013, 46(8):2951~2962.
51. [51]
  [51] W Liu, X Yang, W Huang. J. Colloid Interf. Sci., 2006, 304(1):160~165.
52. [52]
  [52] Y Li, S Sha, Z Wu et al. Colloid Surf. A, 2016, 494:116~124.
53. [53]
  [53] Y Zhang, Z Huang, F Tang et al. Thin Solid Films, 2006, 515(4):2555~2561.
54. [54]
  [54] J Zhang, H Liu, Z Wang et al. Mater. Lett., 2007, 61(23~24):4579~4582.
55. [55]
  [55] C Du, Y Guo, Y Guo et al. J. Mater. Chem. A, 2015, 3(46):23230~23239.
56. [56]
  [56] A G Dong, Y J Wang, Y Tang et al. Chem. Commun., 2002, 4(4):350~351.
57. [57]
  [57] J Zhang, J Liu, S Wang et al. Adv. Funct. Mater., 2004, 14(11):1089~1096.
58. [58]
  [58] D Song, J Zhou, W Jiang et al. Mater. Lett., 2009, 63(2):282~284.
59. [59]
  [59] W Zhang, Y Sun, L Zhang. Ind. Eng. Chem. Res., 2015, 54(25):6480~6488
60. [60]
  [60] J Han, Y Liu, L Li et al. Langmuir, 2009, 25(18):11054~11060.
61. [61]
  [61] S Zhang, W Wu, X Xiao et al. Chem-Asian J., 2012, 7(8):1781~1788.
62. [62]
  [62] L Zhang, N Zhou, B Wang et al. J. Colloid Interf. Sci., 2014, 421(9):1~5.
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