Citation: Li Jia, Liu Bo. Syntheses, Crystal Structure and Properties of a Cadmium Complex containing 2, 5-Thiophene Dicarboxylic Acid and 1, 1'-(1, 4-Butanediyl)Bis(imidazole)[J]. Chemistry, ;2016, 79(11): 1085-1088. shu

Syntheses, Crystal Structure and Properties of a Cadmium Complex containing 2, 5-Thiophene Dicarboxylic Acid and 1, 1'-(1, 4-Butanediyl)Bis(imidazole)

Li Jia ,
Liu Bo

1.
College of Chemistry, Jilin Normal University, Siping 136000

Received Date: 13 May 2016
Available Online: 20 June 2016

A mononuclear cadmium compound, [Cd(bbi)(tdc)(H₂O)]_n·nH₂O [bbi:1, 1'-(1, 4-butanediyl)bis(imidazole); H₂tdc: 2, 5-thiophene dicarboxylic acid] was synthesized at room temperature in the mixed solvent. Its structure was determined by single-crystal X-ray diffraction analysis, and further characterized by IR spectra and elemental analysis. In addition, the thermal stability and the luminescent property of [Cd(bbi)(tdc)(H₂O)]_n·nH₂O have been investigated in detail. The titled complex crystallizes in orthorhombic system, space group Fdd2 with a=20.945(2) Å, b=32.309(4) Å, c=12.1084(14) Å, α=90°, β=90°, γ=90°, V=8194.1(16)Å³, C₁₆H₂₀CdN₄O₆S, M_r=508.82, Z=16, D_c=1.650 g·cm^-³, F(000)=4096, the final R1=0.0186, wR2=0.0491. The Cd ion was coordinated with carboxyl oxygen atoms from H₂tdc ligands to form a one-dimensional (1D) linear chain, and ultimately formed a 3D structure by bbi ligands.
- Crystal structure,
- Thermal stability analysis,
- Luminescent property
1. [1]
  [1] J M Lehn. Supramolecular Chemistry, Concepts and Perspectives. New York:VCH, 1995.
2. [2]
  [2] J W Steed, J L Atwood. Supramolecular Chemistry, New York:Wiley and Sons, 2000.
3. [3]
  [3] B J Holliday, C A Mirkin. Angew. Chem. Int. Ed., 2001, 40:2022~2043.
4. [4]
  [4] B Moulton, M J Zaworotko. Chem. Rev., 2001, 101:1629~1658.
5. [5]
  [5] M Eddaoudi, D B Moler, H Li et al. Acc. Chem. Res., 2001, 34(4):319~330.
6. [6]
  [6] S Leininger, B Olenyuk, P J Stang. Chem. Rev., 2000,100(3):853~908.
7. [7]
  [7] P J Hagrman, D Hagrman, J Zubieta. Angew. Chem. Int. Ed., 1999, 38:2638~2684.
8. [8]
  [8] A J Blake, N R Champness, P Hubberstey et al. Coord. Chem. Rev., 1999, 99:117~183.
9. [9]
  [9] N Stock, S Biswas. Chem. Rev., 2012, 112:933~969.
10. [10]
  [10] B Liu, J Guo, S Zhou et al. Chin. J. Struct. Chem., 2013, 32(2):199~204.
11. [11]
  [11] A Perloff. Inorg. Chem., 1970,(9):2228~2239.
12. [12]
  [12] G M Sheldrick. SHELXS97, Program for Xray crystal structure solution Gottingen University, Germany, 2008.
13. [13]
  [13] G M Sheldrick. SHELXL97, Program for Xray crystal structure refinement Gottingen University, Germany, 2008.
1. [1]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
2. [2]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
3. [3]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
4. [4]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
5. [5]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
8. [8]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
9. [9]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
10. [10]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
11. [11]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
12. [12]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
13. [13]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
14. [14]
  Hao YAN , Meng WANG , Chenyi HU , Ming LI , Chuanjun YUAN . Synthesis of europium complex bonded NaYF₄∶Yb, Er micron-materials and their applications in dual-mode fluorescent development of latent fingerprints. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 991-1002. doi: 10.11862/CJIC.20250302
15. [15]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
16. [16]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
17. [17]
  Xiaoqi LAN , Wei LI , Long JING , Mengyu SU , Xiaoling LUO , Zheng LIU , Qun TANG . Synthesis, crystal structure, and spectral properties of transition-metal-organic frameworks based on thiophene carboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 309-316. doi: 10.11862/CJIC.20250212
18. [18]
  Longfei MA , Fang SI , Congjie PAN , Xinhua WANG . Synthesis and crystal structure of extended tetrathiafulvalene derivatives and cupric bromide charge transfer complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1229-1236. doi: 10.11862/CJIC.20250355
19. [19]
  Junyang FENG , Xiaoli HAN , Yongjie SONG , Gang LI . Proton conduction and fluorescence properties of an ionic hydrogen-bonded organic framework constructed from dibromophthalic acid. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 693-702. doi: 10.11862/CJIC.20250350
20. [20]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(594)
HTML views(69)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142