Citation: Huang Tinghong, Yang Hu, Zhang Chaolan, Yang Guo, Yang Yan. Synthesis, Structural Characterization and Spectroscopic Properties of a Copper(I) Complex Containing Tri-phosphine Ligand with C-H…π and π…π Interactions[J]. Chemistry, ;2016, 79(7): 680-683,687. shu

Synthesis, Structural Characterization and Spectroscopic Properties of a Copper(I) Complex Containing Tri-phosphine Ligand with C-H…π and π…π Interactions

1.
College of Materials and Chemical Engineering, Sichuan University of Science & Engineering, Zigong 643000

Received Date: 28 November 2015
Available Online: 20 January 2016
Fund Project:

A titled complex,[Cu(Triphos)(PPh₃)](BF₄) (1), (Triphos=N,N,N-tris(diphenylphosphino-methyl)amine), was designed and synthesized. The complex was characterized by IR, ¹H NMR, ³¹P NMR, UV-Vis spectrum and X-ray crystal structure analysis. The structural analysis showed each copper (I) is four-coordinated by four P atoms and adopts a distorted-tetrahedral geometry, and the packing structure is controlled by π…π and C-H…π interactions. The maximum absorption at 265 nm and emission centered at 399 nm in acetonitrile solution were also observed for complex 1. The unit cell parameters for complex 1 are as follows, a=12.8072(4) Å, b=14.3693(4) Å, c=25.8438(8) Å, V=4756.0(2) Å³, Z=4.
- Copper (I) complex,
- Crystal structure,
- π-π interaction,
- Spectroscopic
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沈阳化工大学材料科学与工程学院沈阳 110142