Citation: Dong Sijie, Huang Liangliang, Zuo Mengmeng, Zhou Mingdong. Syntheses and Structures of Tetrachloronickelate Benzylimidazolium Salts and Their Activities as Esterifiction Catalyst[J]. Chemistry, ;2016, 79(7): 645-649. shu

Syntheses and Structures of Tetrachloronickelate Benzylimidazolium Salts and Their Activities as Esterifiction Catalyst

1.
College of Chemistry, Chemical Engineering and Enviromental Engineering, Liaoning Shihua University, Fushun 113001

Corresponding author: Zhou Mingdong,
Received Date: 17 November 2015
Available Online: 28 February 2016
Fund Project:

Three tetrachloronickelate benzylimidazolium salts were synthesized and characterized by IR spectroscopy, elemental analysis, nuclear magnetic resonance, and single crystal X-ray diffraction analysis. Further more, the compounds were applied as catalysts for oxidative esterification of aldehydes with alcohol. The experimental results showed that tetrachloronickelate benzylimidazolium salt exhibited high catalytic activity in oxidative esterification reaction. Under the optimal reaction conditions, the 80% yield of methyl benzoate was obtained by using 4-methylbenzylimidazolium tetrachloronickelate as catalyst.
- Tetrachloronickelate,
- Structure,
- Catalysis,
- Esterfication
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沈阳化工大学材料科学与工程学院沈阳 110142