Citation: Liu Lei, Lv Haijun, Wang Mengyan, Chen Aibing, Yu Yifeng, Wang Lili, Wang Binbin. AIE Properties of Small Linear Conjugated Compounds Based on RIR[J]. Chemistry, ;2016, 79(1): 43-47. shu

AIE Properties of Small Linear Conjugated Compounds Based on RIR

Liu Lei ^1,2 ,
Lv Haijun ¹ ,
Wang Mengyan ¹ ,
Chen Aibing ¹ ,
Yu Yifeng ¹ ,
Wang Lili ¹ ,
Wang Binbin ¹

1.
1. Hebei Research Center of Pharmaceutical and Chemical Engineering, College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018;
2.
2. Hebei Key Laboratory of Molecular Chemistry for Drug, Shijiazhuang 050018

Received Date: 20 June 2015
Available Online: 13 July 2015
Fund Project:

In this article, six linear molecules including 4-butyl-1,1'-biphenyl (L1), 4,4'-diisopropyl-1,1'-biphenyl (L2), 5,5'-dimethyl-2,2'-bipyridine (L3), 2-([1,1'-biphenyl]-4) thiophene (L4), 1,1'-binaphthyl (L5), and 5-phenyl-2,2'-bithiophene (L6) were synthesized. Their luminescent properties were studied by UV-Vis and fluorescence spectra. The results revealed that compound L1, L2 and L3 show AIE properties, while L4, L5, L6 show ACQ properties. We extrapolated that biphenyl-like compounds are AIE active, and restriction of intramolecular rotation (RIR) in the aggregates is the cause for the AIE effect. But linear molecules with more or larger aromatic rings show ACQ phenomena.
- Aggregation-induced-emission,
- Linear,
- Conjugate,
- Fluorescence
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