Citation: Guo Xiaolong, Wang Luyao, Li Lu, Zhang Bingsen. Application of Immobilized Ionic Liquids in Organic Syntheses[J]. Chemistry, ;2016, 79(1): 16-22. shu

Application of Immobilized Ionic Liquids in Organic Syntheses

1.
Department of Chemistry, Capital Normal University, Beijing 100089

Corresponding author: Wang Luyao,
Received Date: 25 February 2015
Available Online: 9 August 2015
Fund Project:

The immobilized ionic liquid is the combination of the ionic liquid and support material, in which two distinct parts are connected by two different interaction forces, one is the physisorption of ionic liquids to the supporting surface, such as Vander Waals, hydrogen bonding etc, and the other is chemisorption of the ionic liquids to the surface, such as covalent bonding. The immobilized ionic liquid remains the main advantages of ionic liquid, and has higher catalytic activity and better reusability. This novel catalyst can be used in many organic reactions, such as condensation reaction, coupled reaction and asymmetric synthesis. This article describes the variety of immobilized materials, interaction forces between support material and ionic liquid, and the applications of immobilized ionic liquids in organic synthesis as catalyst.
- Immobilized ionic liquids,
- Catalysis,
- Organic synthesis
1. [1]
  [1] T Welton. Chem. Rev., 1999, 99:2071~2083.
2. [2]
  [2] 于佳音, 于洪峰. 科技资讯, 2010, 25:8.
3. [3]
  [3] A C Cole, J L Jensen, I Ntai et al. J. Am. Chem. Soc., 2002, 124, 5962~5963.
4. [4]
  [4] N Yan, Y Yuan, R Dykema et al. Angew. Chem. Int. Ed., 2010, 49(32):5549~5553.
5. [5]
  [5] W Wardencki, J Curyło, J Namies'nik. J. Biochem. Bioph. Methods, 2007, 70(2):275~288.
6. [6]
  [6] P Matejtschuk, K Malik, C Duru et al. Am. Pharm. Rev., 2009, 12:12~18.
7. [7]
  [7] X Duan, M Zhang, A S Mujumdar et al. Drying Technol., 2010, 28:444~453.
8. [8]
  [8] J J Schwegman. Innov. Pharm. Technol., 2009, 29:72~74, 76~77.
9. [9]
  [9] L A Gatlin, T Auffret, E Y Shalaev et al. Drugs Pharm. Sci., 2008, 175:177~195.
10. [10]
  [10] S Werner, N Szesni, M Kaiser et al. Chem. Eng. Technol., 2012, 35(11):1962~1967.
11. [11]
  [11] K B Sidhpuri, A L Daniel-da-Silva, T Trindade et al. Green Chem., 2011, 13(2):340~349.
12. [12]
  [12] 彭长宏, 余芳, 程晓苏. 环境科学与技术, 2011, 34(9):114~118.
13. [13]
  [13] C DeCastro, E Sauvage, M H Valkenberg et al. J. Catal., 2000, 196(1):86~94.
14. [14]
  [14] S Rostamnia, H C Xin. J. Mol. Liq., 2014, 195:30~34.
15. [15]
  [15] V Polshettiwar, R Luque, A Fihri et al. Chem. Rev., 2011, 111(5):3036~3075.
16. [16]
  [16] S Shylesh, V Schuenemann, W R Thiel. Angew. Chem. Int. Ed. 2010, 49(20):3428~3459.
17. [17]
  [17] J Deng, L P Mo, F Y Zhao et al.Green Chem., 2011, 13(9):2576~2584.
18. [18]
  [18] P H Li, B L Li, Z M An et al. Adv. Synth. Catal., 2013, 355(14~15):2952~2959.
19. [19]
  [19] F P Ma, P H Li, B L Li et al. Appl. Catal. A:Gen., 2013, 457:34~41.
20. [20]
  [20] Y Li, J S Wu,D W Qi et al. Chem. Commun., 2008, 5:564~566.
21. [21]
  [21] M Zhang, Y P Wu, X Z Feng et al. J. Mater. Chem., 2010, 20(28):5835~5842.
22. [22]
  [22] J L Lyon, D A Fleming, M B Stone et al. Nano Lett., 2004, 4(4):719~723.
23. [23]
  [23] Q Zhang, H Su, J Luo. Green Chem., 2012, 14:201~208.
24. [24]
  [24] S M Sadeghzadeh, F Daneshfar. J. Mol. Liq., 2014, 199:440~444.
25. [25]
  [25] J B Tang, H D Tang, W L Sun et al. J. Polym. Sci. Part A:Polym. Chem., 2005, 43:5477~5489.
26. [26]
  [26] J Y Yuan, M Antonietti. Polymer, 2011, 52(7):1469~1482.
27. [27]
  [27] V Sans, N Karbass, M I Burguete et al. Chem.Eur. J. 2011, 17, 1894~1906.
28. [28]
  [28] S S Shinde, S N Patil. Org. Biomol. Chem., 2014, 12(45):9264~9271.
29. [29]
  [29] M Chtchigrovsky, A Primo, P Gonzalez et al. Angew. Chem. Int. Ed., 2009, 48:5916~5920.
30. [30]
  [30] A Ricci, L Bernardi, C Gioia et al. Chem. Commun., 2010, 46:6288~6290.
31. [31]
  [31] J Sun, J Q Wang, W G Cheng et al. Green Chem., 2012, 14(3):654~660.
32. [32]
  [32] M Ruta, I Yuranov, P J Dyson. J. Catal., 2007, 247(2):269~276.
33. [33]
  [33] L J Lozanoa, C Godínez, A P de los Ríos et al. J. Membr. Sci., 2011, 376(1~2):1~14.
34. [34]
  [34] S K Movahed, R Esmatpoursalmani, A Bazgir. RSC Adv., 2014, 49(28):14586~14591.
35. [35]
  [35] N M Jiao, Y Wang et al. RSC Adv. 2015,5(34):26913~26922.
36. [36]
  [36] J Isaad. RSC Adv., 2014, 4(90):49333~49341.
37. [37]
  [37] S Rostamizadeh, M Nojavan, R Aryan et al. Catal. Lett., 2014, 144(10):1772~1783.
38. [38]
  [38] A Khalafi-Nezhad, S Mohammadi. ACS Comb. Sci., 2013, 15(9):512~518.
39. [39]
  [39] S Rostamnia, A Hassankhani, H G Hossieni et al. J. Mol. Catal. A:Chem., 2014, 395, 463~469.
40. [40]
  [40] A Pourjavadi, S H Hosseini, M Doulabi et al. ACS Catal., 2012, 2(6):1259~1266.
41. [41]
  [41] P H Li, L Wang, Y C Zhang et al. Tetrahedron, 2008, 64(32):7633~7638.
42. [42]
  [42] X Zhang, W S Zhao, C K Qu et al. Tetrahed.:Asym., 2012, 23(6~7):468~473.
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沈阳化工大学材料科学与工程学院沈阳 110142