Citation: Cui Xuanxuan, Li Ruifeng, Zhu Yinming, Xiao Xunwen. Synthesies, Structures and Properties of TTF Derivatives with Benzoyloxy[J]. Chemistry, ;2016, 79(3): 272-275. shu

Synthesies, Structures and Properties of TTF Derivatives with Benzoyloxy

1.
1. Department of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024;
2.
2. Department of Chemical Engineering, Ningbo University Technology, Ningbo 315016

Corresponding author: Xiao Xunwen,
Received Date: 28 September 2015
Available Online: 12 November 2015
Fund Project:

Two tetrathiafulvalenes substituted with a phenyl (Ph) (TTF-A) [A=Ph-COOCH₃ (7) and A=Ph-COOH (8)] have been synthesized to clear the nature of the donor-acceptor interaction between the TTF unit and the acceptor group. Their structures were characterized by ¹H NMR,¹³C NMR and mass spectra. The synthesized compounds both display two reversible redox peaks corresponding to the TTF/TTF^+· and TTF^+·/TTF²⁺ and show the similar redox potentials comparable to other Ph-substituted TTF derivatives. And the results indicated that compound 7 and 8 are good donor molecules. We also got the crystal of the key intermediate 5 for the synthesis of compound 7 and 8. Compound 5 belongs to monoclinic space group Pc with cell parameters of a=0.3890 (1) nm, b=1.065 (1) nm, c=1.318 (1) nm, Z=2, V=534.5 (2) nm³, D_c=1.542 g·cm^-3,F(000)=260,R=0.0467, ωR=0.0739 (I>2σ(I)).
- TTF,
- Donor-acceptor interaction,
- Redox property,
- Crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142