Citation:
Liu Xingpeng, Hong Tao, Huang Kama. The Polarization of Chemical Reactions under the Action of Electromagnetic Wave[J]. Chemistry,
;2016, 79(4): 377-380.
-
Microwave-assisted chemical reactions have attracted interest for decades, but hot spots and thermal runaway prevent the further development of microwave heating in chemical engineering. In order to solve these problems, it is needed to study the interaction between electromagnetic wave and chemical reactions. The polarization of the chemical reactions is the basis to investigate the interaction between electromagnetic wave and chemical reactions. The expression of polarization of the polar-molecule reactions is derived with modified Smoluchowski-Debye equation. The polarization of the chemical reactions is actually a response of a linear time varying system, which is a Markov process under certain conditions. The aim of this paper is to discuss the relation between the time domain and the frequency domain representation of the polarization of chemical reactions, along with the limitations of the representation in the frequency domain.
-
-
-
[1]
[1] R Gedye, F Smith, K Westaway et al. Tetrahed. Lett, 1986, 27:279~282.
-
[2]
[2] D A Jones, T P Lelyveld, S D Mavrofidis et al. Resour. Conserv. Recy., 2002, 34:75~90.
-
[3]
[3] T Santos, M A Valente, J Monteiro et al. Appl. Therm. Eng., 2011, 31:3255~3261.
-
[4]
[4] R Vadivambal, D S Jayas. Food Bioproc. Tech., 2010, 3:161~171.
-
[5]
[5] X Zhang, D O Hayward, D M P Mingos. Catal. Lett., 2003, 88:33~38.
-
[6]
[6] C O Kappe. Chem. Soc. Rev., 2008, 37:1127~1139.
-
[7]
[7] G Roussy, A Bennani, J M Thiebaut. J. Appl. Phys., 1987, 62:1167~1170.
-
[8]
[8] H Lehmann, L LaVecchia. Org. Proc. Res. Dev., 2010, 14:650~656.
-
[9]
[9] C O Kappe, B Pieber, D Dallinger. Angew. Chem. Int. Ed., 2013, 52:1088~1094.
-
[10]
[10] S Sudo, N Oshiki, N Shinyashiki et al. J. Phys. Chem. A, 2007. 111:2993~2998.
-
[11]
[11] S Sun, X Hu, Y Xia. Appl. Biochem. Biotech., 2012, 166:1454~1462.
-
[12]
[12] W Scheider. Biophys. J., 1965, 5:617~628.
-
[13]
[13] G Schwarz. J. Phys. Chem., 1967, 71:4021~4030.
-
[14]
[14] K Huang, H Zhu, L Wu. Bioresour. Technol., 2013, 131:541~544.
-
[15]
[15] H C Zhu, X Q Yang, K M Huang. J. Solut. Chem., 2012, 41:1729~1737.
-
[16]
[16] X Yang, K Huang. IEEE Trans. Geosci. Remote, 2005, 43:315~320.
-
[17]
[17] K M Huang, X Yang. PIER, 2008, 5:99~107.
-
[18]
[18] T Hong, K Huang. J. Phys. Org. Chem., 2015, 28:414~417.
-
[19]
[19] K Huang, T Hong. J. Phys. Chem. A, 2015, 119:8898~8902.
-
[20]
[20] W T Coffey, B V Paranjape. P. Roy. Soc. A-Math. Phys., 1978, 78:17~25.
-
[21]
[21] G H Czerlinski. Chemical relaxation, New York:Dekker, 1966.
-
[22]
[22] Z Sekkat, J Wood, W Knoll. J. Phys. Chem., 1995, 99:17226~17234.
-
[23]
[23] 李景德,沈韩,陈敏. 电介质理论. 北京:科学出版社, 2003. 63~69.
-
[24]
[24] S R de Groot, P Mazur. Non-equilibrium thermodynamics, North Chelmsford:Courier Corporation, 2012.
-
[25]
[25] C Dykstra, G Frenking, K Kim et al. Theory and applications of computational chemistry:the first forty years. Amsterdam:Elsevier, 2011.
-
[26]
[26] 李如生. 平衡和非平衡统计力学. 北京:清华大学出版社, 1995:171~202.
-
[27]
[27] N G van Kampen. Stochastic processes in physics and chemistry. Amsterdam:Elsevier, 1992.
-
[28]
[28] C T Chen. Linear system theory and design. New York Oxford:Oxford University Press, 1995.
-
[1]
-
-
-
[1]
Gengyuan Li , Yexin Wang , Song Gao , Shangda Jiang . Advances in Light-Induced Spin Polarization of Magnetic Molecules. University Chemistry, 2025, 40(12): 87-94. doi: 10.12461/PKU.DXHX202509112
-
[2]
Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi2MoO6 Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
-
[3]
Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . Rationally Designed ZnFe1.2Co0.8O4/BiVO4 S-Scheme Heterojunction with Spin-Polarization for the Elimination of Antibiotic. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-0. doi: 10.1016/j.actphy.2025.100050
-
[4]
Xie Yao , Li Shuangjun , Chen Chao , Fan Siyu , Tao Ying , Zhang Qitao . Ionic polarization engineering of polymeric carbon nitride toward efficient H2O2 photosynthesis. Acta Physico-Chimica Sinica, 2026, 42(5): 100183-. doi: 10.1016/j.actphy.2025.100183
-
[5]
Zhongning Tian , Jinyuan Liu , Meng Zhang , Qianqian Jia , Mingbo Liu , Zhenjiang Li , Ting Wang , Wenjie Zhao , Dongwei Ma , Xueli Qi . Constructing selenium-vacancy-rich SiC@CoSe2−x nanocomposites to boost dipole and interfacial polarization for electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(8): 100323-0. doi: 10.1016/j.actphy.2026.100323
-
[6]
Zirui Jia , Zehua Zhou , Shuang Xu , Yuan Wang , Mengjia Shi , Mengting He , Chuankun Zhang , Di Lan . Two birds with one stone: phosphorus doping to enhance conduction loss and dipole polarization for electromagnetic wave absorber. Acta Physico-Chimica Sinica, 2026, 42(8): 100310-0. doi: 10.1016/j.actphy.2026.100310
-
[7]
Zhiqing Jia , Xinju Gong , Di Lan , Huanhuan Sun , Yu Liu , Yuping Gao , Siyao Guo . Electrostatically induced dual-coupled interfaces of defect polarization enhanced PBA/MXene heterostructures for boosting electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(8): 100312-0. doi: 10.1016/j.actphy.2026.100312
-
[8]
Guangrong Wu , Jiahui Zhu , Xiaomeng Guo , Changmiao Zhang , Mengting He , Hua Qiu , Dongwei Ma . Construction of Schottky barrier and the enhanced interface polarization effect of C@ZnO/Sn@GaN for high performance electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(8): 100324-0. doi: 10.1016/j.actphy.2026.100324
-
[9]
Chunfang Zhang , Yuehua Liu , Lin Yang , Wenhui Xu , Mingtao Run , Cuimiao Zhang . 醋酸电离平衡常数测定实验的改进. University Chemistry, 2026, 41(5): 131-140. doi: 10.12461/PKU.DXHX202511002
-
[10]
Na Li , Limin Shao . Deduction of the General Formula of the Inverse Function of the Titration Curve. University Chemistry, 2025, 40(3): 390-401. doi: 10.12461/PKU.DXHX202409134
-
[11]
Shuying Zhu , Shuting Wu , Ou Zheng . Improvement and Expansion of the Experiment for Determining the Rate Constant of the Saponification Reaction of Ethyl Acetate. University Chemistry, 2024, 39(4): 107-113. doi: 10.3866/PKU.DXHX202310117
-
[12]
Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
-
[13]
Ying Xiong , Guangao Yu , Lin Wu , Qingwen Liu , Houjin Li , Shuanglian Cai , Zhanxiang Liu , Xingwen Sun , Yuan Zheng , Jie Han , Xin Du , Chengshan Yuan , Qihan Zhang , Jianrong Zhang , Shuyong Zhang . Basic Operations and Specification Suggestions for Determination of Physical Constants of Organic Compounds. University Chemistry, 2025, 40(5): 106-121. doi: 10.12461/PKU.DXHX202503079
-
[14]
Jian Huang , Mingjue Zhang , Shangchu Ma , Jia Dong , Guanzi Wu , Aiming Wen , Zhuoliang Liu . Data-Driven Approach for the Determination of Chemical Reaction Rate Constant. University Chemistry, 2026, 41(1): 213-226. doi: 10.12461/PKU.DXHX202505110
-
[15]
Yu Dai , Xueting Sun , Haoyu Wu , Naizhu Li , Guoe Cheng , Xiaojin Zhang , Fan Xia . Determination of the Michaelis Constant for Gold Nanozyme-Catalyzed Decomposition of Hydrogen Peroxide. University Chemistry, 2025, 40(5): 351-356. doi: 10.12461/PKU.DXHX202407052
-
[16]
Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
-
[17]
Yichang Liu , Li An , Dan Qu , Zaicheng Sun . “双碳”背景下的综合设计实验——以PbCrO4催化甲基蓝的光降解速率常数测定为例. University Chemistry, 2025, 40(6): 222-229. doi: 10.12461/PKU.DXHX202407105
-
[18]
Haiying Jiang , Huilin Guo , Yongliang Cheng , Tongyu Xu , Jiquan Liu , Mingli Peng . Teaching Design of the Nernst Equation Based on the “Flipped Classroom” Method. University Chemistry, 2024, 39(8): 84-90. doi: 10.3866/PKU.DXHX202312091
-
[19]
Xintian Xie , Sicong Ma , Yefei Li , Cheng Shang , Zhipan Liu . Application of Machine Learning Potential-based Theoretical Simulations in Undergraduate Teaching Laboratory Course Design. University Chemistry, 2025, 40(3): 140-147. doi: 10.12461/PKU.DXHX202405164
-
[20]
Sihan Wang , Chenxi Yu , Shuzhang Ran , Jiawei Chen , Shoutong Rao , Xinyi Liang , Ruiqi Dong , Guixiang Zeng , Guoqiang Wang , Jing Ma . 铁配合物合成与性质探究的数智化改进——大学化学实验中“磺基水杨酸合铁配合物的组成与稳定常数的测定”的创新设计. University Chemistry, 2026, 41(5): 36-49. doi: 10.12461/PKU.DXHX202511137
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(1077)
- HTML views(159)
Login In
DownLoad: