Citation: Fu Nihong, Yuan Yuguo, Wang Jingyun, Zang Shuliang. Preparation of 5-Hydroxymethylfurfural from Cellulose Degradation Catalyzed by Acidic Ionic Liquids[J]. Chemistry, ;2016, 79(4): 355-359. shu

Preparation of 5-Hydroxymethylfurfural from Cellulose Degradation Catalyzed by Acidic Ionic Liquids

1.
1. School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Technology, Fushun 113001;
2.
2. School of Mining Engineering, Liaoning University of Petroleum and Chemical Technology, Fushun 113001

Corresponding author: Wang Jingyun,
Received Date: 6 July 2015
Available Online: 10 October 2015
Fund Project:

In this study, imidazolium based acidic ionic liquids and CrCl₃·6H₂O were used to catalyze the hydrolysis of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride ([Amim]Cl) via microwave-assisted irradiation to prepare 5-hydroxymethyl furfural (5-HMF). The effects of the type and amount of catalysts, reaction temperature and time, amount of water on the degradation of cellulose were studied in details. The results indicated that [C₂mim]HSO₄ and CrCl₃·6H₂O are efficient catalysts for preparing 5-HMF. The cellulose can be completely converted with the highest TRS yield of 87.22% and 5-HMF yield of 50% under the condition of n_MCC:n_Cr=10:1, the mass of [C₂mim]HSO₄=0.02g, and reaction temperature 160℃ under microwave-assisted heating for 30 min.
- Acidic ionic liquids,
- Degradation,
- Cellulose,
- 5-Hydroxymethyl furfural
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沈阳化工大学材料科学与工程学院沈阳 110142