Citation: Zhao Xianmei, Che Yuanyuan, Ding Sheng, Liu Lang. Structures and Emission Properties of Three Isomers of 1,3-Diphenyl-5-pyrazolone[J]. Chemistry, ;2016, 79(10): 952-957,980. shu

Structures and Emission Properties of Three Isomers of 1,3-Diphenyl-5-pyrazolone

1.
School of Chemistry and Chemical Engineering;Institute of Applied Chemistry, Key Laboratory of Energy Materials Chemistry, Ministry of Education, Xinjiang University, Urumqi 830046

Corresponding author: Liu Lang,
Received Date: 27 February 2016
Available Online: 20 April 2016
Fund Project:

Three isomers of 1,3-diphenyl-5-pyrazolone (DPP) with different color were obtained by recrystallization using three different solvents. Their composition and structures were characterized by IR, ¹H NMR, X-ray powder diffraction analysis. Their emission properties were studied by fluorescence spectra. The results indicated that these isomers exhibit aggregation-induced emission and photoisomerization behavior. Moreover, the recrystallization solvents can obviously affect the structure and property of the products. In addition, the composited film of DPP/polystyrene also exhibits good fluorescence property, indicating it has potential application in the field of antifake.
- Pyrazolone,
- Recrystallization,
- Aggregation-induced emission,
- Isomers,
- Film
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