Citation: Guo Jixi, Song Xianli, Guo Mingxi, Jia Dianzeng, Tong Fenglian. Preparation of MnO₂/CBCNFs Composite Materials and Its Electrochemical Performance for Flexible Supercapacitor[J]. Chemistry, ;2016, 79(10): 942-946,951. shu

Preparation of MnO₂/CBCNFs Composite Materials and Its Electrochemical Performance for Flexible Supercapacitor

1.
Key Laboratory of Energy Materials Chemistry, Ministry of Education;Key Laboratory of Advanced Functional Materials, Autonomous Region;Institute of Applied Chemistry, Xinjiang University, Urumqi 830046

Corresponding author: Jia Dianzeng,
Received Date: 27 March 2016
Available Online: 18 May 2016
Fund Project:

The flexible coal based carbon nanofibers (CBCNFs) were prepared by electrospinning technique and well modified by using the low temperature plasma surface modification technology. The CBCNFs/MnO₂ composite was prepared by in situ reduction reaction using plasma-modified CBCNFs as reductant to react with potassium permanganate (KMnO₄). The morphology and structure of as-prepared CBCNFs/MnO₂ composites were investigated by X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM, TEM). The results showed that the nanoflakes of MnO₂well coated on the CBCNFs. Furthermore, the electrochemical performance of the electrode material as flexible supercapacitor was investigated. The prepared material (CBCNFs/MnO₂-2) with KMnO₄/CBCNFs=2/1(mass ratio) shows good electrochemical performance. It was found that the CBCNFs/MnO₂-2 electrodes showed a specific capacitance of 118 F·g^-1 at a current density of 0.1 A·g^-1, which is 4.5 times higher than that of the CBCNFs (26 F·g^-1). The capacitance retention ratio of the CBCNFs/MnO₂-2 remained 97% after 1000 cycles at a current density of 1 A·g^-1.
- Electrospinning,
- Coal based carbon nanofibers,
- Plasma,
- MnO₂,
- Flexible supercapacitor
1. [1]
  [1] Y L Shao, M F El-Kady, L J Wang et al. Chem. Soc. Rev., 2015, 44(11):3639~3665.
2. [2]
  [2] J Bae, M K Song, Y J Park et al. Angew. Chem. Int. Ed., 2011, 50(7):1683~1687.
3. [3]
  [3] M H Yu, T Zhai, X H Lu et al. J. Power Sources, 2013, 239:64~71.
4. [4]
  [4] B D Assresahegn, D Bélanger. Adv. Funct. Mater., 2015., 25(43):6775~6785.
5. [5]
  [5] G P Wang, L Zhang, and J J Zhang. Chem. Soc. Rev., 2012, 41(2):797~828.
6. [6]
  [6] C Liu, F Li, L P Ma et al. Adv. Mater., 2010, 22(8):28~62.
7. [7]
  [7] P Simon, Y Gogotsi. Nat. Mater., 2008,7:845~854.
8. [8]
  [8] M Huang, F Li, F Dong et al. J. Mater. Chem. A, 2015, 3(43):21380~21423.
9. [9]
  [9] T F Huang, Z H Qiu, D W Wu et al. Int. J. Electrochem. Sci., 2015,10:6312~6323.
10. [10]
  [10] S J He, W Chen. J. Power Sources, 2015, 294:150~158.
11. [11]
  [11] J H Zhang, Y H Wang, J B Zang et al. Carbon, 2012, 50(14):5196~5202.
12. [12]
  [12] T Wang, D F Song, H Zhao et al. J. Power Sources, 2015, 274:709~717.
13. [13]
  [13] D Zhou, H M Lin, F Zhang et al. Electrochim. Acta, 2015,161:427~435.
14. [14]
  [14] M Sawangphruk, P Srimuk, P Chiochan et al. Carbon, 2013, 60:109~116.
15. [15]
  [15] Y J Kang, B Kim, H Chung et al. Synth. Met., 2010, 160(23):2510~2514.
16. [16]
  [16] H Y Zhao, L X Wang, D Z Jia et al. J. Mater. Chem. A, 2014, 2(24):9338~9344.
17. [17]
  [17] M X Guo, J X Guo, D Z Jia et al. J. Mater. Chem. A, 2015, 3(42):21178~21184.
1. [1]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
2. [2]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
5. [5]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . 二维材料基超级电容器的容量与倍率性能提升策略. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
6. [6]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
7. [7]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
10. [10]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
11. [11]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
12. [12]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
13. [13]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
14. [14]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
15. [15]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
16. [16]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
17. [17]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
18. [18]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
19. [19]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
20. [20]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(413)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of MnO2/CBCNFs Composite Materials and Its Electrochemical Performance for Flexible Supercapacitor

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of MnO₂/CBCNFs Composite Materials and Its Electrochemical Performance for Flexible Supercapacitor