Citation: HUANG Guo-bao, WANG Zhi-qing, LI Qing-feng, HUANG Jie-jie, FANG Yi-tian. Syngas methanation over nickel catalyst in liquid-phase[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(8): 952-957. shu

Syngas methanation over nickel catalyst in liquid-phase

1.
1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: LI Qing-feng,
Received Date: 18 February 2014
Available Online: 29 March 2014
Fund Project: 国家自然科学基金青年科学基金(21106173) (21106173)中国科学院战略性先导科技专项(XDA07050100) (XDA07050100)山西省青年科技研究基金(2013021007-2) (2013021007-2)中国科学院山西煤炭化学研究所青年人才项目(2011SQNRC01)。 (2011SQNRC01)

Unsupported metal nickel catalysts were prepared by liquid phase reduction method. The catalytic performance of the catalysts for syngas methanation were conducted in an autoclave using decalin as the hydrogen donor solvent at different operation conditions, such as temperature, mol ratio of H₂/CO in feed gas. And the catalyst characterizations were conducted by means of XRD, SEM, H₂-TPR.The results showed that the content of CH₄ in the product gas was 89.39% when 2% catalyst was used at 330 ℃, and the corresponding conversions of CO and H₂ were 94.56% and 92.60%, respectively. When 4% catalyst was used, the CO conversion was further improved to more than 99% while the content of CH₄ in the product gas exceeded 94.26%. The best operation temperature of syngas methanation in liquid phase was 330 ℃and the optimum range of H₂/CO mol ratio in feed was 2.20~2.67.
- syngas methanation reaction,
- decalin,
- hydrogen donation solvent,
- nickel catalyst
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