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Citation: ZUO Chen-sheng, Zhou Si-yu, SUN Cheng-zhi, WANG Xing-zhi, LIU Dao-sheng, SEO Hwi-min, PARK Yong-ki, GUI Jian-zhou, LIU Dan. Preparation and application of magnesium-based CO2 sorbent for temperature swing absorption I.Na/Mg mol ratio[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(7): 884-889. shu

Preparation and application of magnesium-based CO2 sorbent for temperature swing absorption I.Na/Mg mol ratio

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    1. Division of Chemistry, Chemical Engineering and Environment, Liaoning Shihua University, Fushun 113001, China;

  • Corresponding author: GUI Jian-zhou,  LIU Dan, 
  • Received Date: 16 December 2013
    Available Online: 21 March 2014

    Fund Project: 国家自然科学基金(21103077) (21103077)教育部新世纪优秀人才支持计划(NCET-11-1011) (NCET-11-1011)韩国教育科技部KCRC2020项目(2012M1A8A1912543) (2012M1A8A1912543)天津市应用基础与前沿技术研究计划(13JCYBJC41600) (13JCYBJC41600)辽宁省自然科学基金(201202123) (201202123)辽宁省教育厅(L2012128)。 (L2012128)

  • A series of magnesium-based CO2 absorbents with different Na/Mg molar ratios were prepared by precipitation method with Mg(NO3)2 and Na2CO3 as raw materials, and characterized by various methods (including XRD, SEM-EDS and DTG) to study the compositions, morphology and decomposition temperature and so on. The CO2 absorption performance was evaluated by temperature swing absorption-desorption dynamic cyclic tests to check the impact of Na/Mg molar ratio. It can be seen that optimum molecular ratio of Na to Mg is 8.15, and the sorbents is homogeneous with lower decomposition temperature caused by small particles of the sample, and initial CO2 adsorption capacity can reach 9.584%. Good recycling capability can be obtained as well. Compared with the initial absorption capacity, there was only 4.2% decrease after 20 recycles.
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