Citation: YAN Heng, ZHANG Jun-ying, WANG Zhing-liang, ZHAO Yong-chun, TIAN Chong, ZHENG Chu-guang. CO₂ sequestration by direct mineral carbonation of serpentine under medium and low pressure[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(6): 748-753. shu

CO₂ sequestration by direct mineral carbonation of serpentine under medium and low pressure

1.
1. State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China;

Corresponding author: ZHANG Jun-ying,
Received Date: 21 November 2012
Available Online: 28 January 2013
Fund Project: 国家自然科学基金(40972102,41172140) (40972102,41172140)国家重点基础研究发展规划(973计划,2011CB201500)。 (973计划,2011CB201500)

Serpentine was used as the mineral material for CO₂ sequestration by direct mineral carbonation under medium and low pressure. A series number of experiments were carried out to investigate the factors that influence the conversion of carbonation reaction, such as temperature, pressure, particle size, solution composition and pretreatment. The results show that serpentine can be used to sequestrate CO₂ in simulated flue gas by aqueous direct mineral carbonation under medium and low pressure. Carbonation conversion increases with increasing temperature and pressure. Decrease in mineral particle sizes and use of heat treatment before carbonation can effectively improve the conversion. The addition of NaHCO₃, which has a buffering effect that kept the solution pH in a certain range, can also improve the carbonation conversion. The highest carbonation conversion of 47.7% and 36.3% was obtained in 60 min under 4 MPa and 150℃ for pure CO₂ gas and simulated flue gas, respectively.
- medium and low pressure,
- carbon dioxide,
- direct mineral carbonation,
- serpentine,
- sequestration
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沈阳化工大学材料科学与工程学院沈阳 110142

CO2 sequestration by direct mineral carbonation of serpentine under medium and low pressure

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通讯作者: 陈斌, bchen63@163.com

CO₂ sequestration by direct mineral carbonation of serpentine under medium and low pressure