Citation: Fu-Min Xue, Ming-Hui Liang, Zhen-Hua Wang, Ling-Yu Luan, Fu-Wei Li, Yan Cheng, Guang-Sheng Shao. The preparation and performance of visible-light-sensitized luminescent nanoparticles based on europium complex[J]. Chinese Chemical Letters, ;2014, 25(2): 247-252. shu

The preparation and performance of visible-light-sensitized luminescent nanoparticles based on europium complex

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a Shandong Provincial Analysis and Test Center, ShanDong Academy of Science, Jinan 250014, China;
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b National Center for Nanosicence and Technology, Beijing 100190, China;
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c China Banknote Ink Company, Shanghai 201315, China

Corresponding author: Fu-Min Xue,
Received Date: 30 September 2013
Available Online: 15 October 2013
Fund Project:

Long-wavelength-sensitized luminescent materials are desired for bio-detection. In this paper, we prepared a new kind of luminescent europium nanoparticles by a co-precipitation-condensation method. The luminescent europiumcomplex Eu(tta)₃·bpt (tta = thenoyltrifluoroacetonate; bpt = 2-(N,N-di- ethylanilin-4-yl)-4,6-bis(pyrazol-1-yl)-1,3,5-triazine) was used as the active material, being encapsulated in the nanoparticles formed from 1H, 1H, 2H, 2H-perfluorooctyltrimethoxysilane (PFOTS) and poly(styrene-co-methyl methacrylate) [P(ST-co-MMA)]. The prepared nanoparticles not only can be well dispersed in water but also were of high photostability. Importantly, the nanoparticles displayed maximal excitation wavelength at 425 nm as well as an extended excitation wavelength up to 480 nm and a quantum yield for Eu³⁺ luminescence of 0.22 (λ_ex = 425 nm, room temperature).
- Long-wavelength-sensitized luminescence,
- Europium nanoparticles,
- Co-precipitation-condensation,
- Bio-detection
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