Citation: Xing-Wei Wang, Hui Guo, Meng-Jie Liu, Xin-Yi Wang, Dong-Sheng Deng. 2D Naphthalenedisulfonate-cadmiun coordination polymer with 2, 4, 5-tri(4-pyridyl)-imidazole as a co-ligand：Structure and catalytic property[J]. Chinese Chemical Letters, ;2014, 25(2): 243-246. shu

2D Naphthalenedisulfonate-cadmiun coordination polymer with 2, 4, 5-tri(4-pyridyl)-imidazole as a co-ligand：Structure and catalytic property

Xing-Wei Wang ^a,b ,
Hui Guo ^b ,
Meng-Jie Liu ^a,b ,
Xin-Yi Wang ^a,, ,
Dong-Sheng Deng ^a,b,,

1.
a Institute of Resources & Environment, Henan Polytechnic University, Jiaozuo 454150, China;
2.
b College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: Xin-Yi Wang, Dong-Sheng Deng,
Received Date: 29 July 2013
Available Online: 8 November 2013
Fund Project: We gratefully acknowledge the financial support from the National Natural Science Foundation of China (No.21272109) (No.21272109) the Natural Science Foundation of Henan Province (No.112300410138) (No.112300410138) and Luoyang Science and Technology Fund. (No.2011B150021)

A new 2D coordination polymer, [Cd(tpim)(1,5-nds)]_n(1), was constructed from 1,5-naphthalenedisulfonate (1,5-nds), 2,4,5-tri(4-pyridyl)-imidazole (tpim) and Cd(CH₃COO)₂·2H₂O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of 1 in the solid state were also investigated.
- Crystal structure,
- Organosulfonate,
- Coordination polymer,
- Epoxide ring-opening
1. [1]
  [1] H.L. Jiang, Q. Xu, Porous metal-organic frameworks as platforms for functional applications, Chem. Commun. 47 (2011) 3351-3370.
2. [2]
  [2] T. Rahi, M. Baghernejad, K. Niknam, Synmesis of a-aminonitriles using silicabonded N-propylpiperazine sulfamic acid as a recyclable catalyst, Chin. Chem. Lett. 23 (2012) 1103-1106.
3. [3]
  [3] H.H. Wu, Z.M. Zhang, E.B. Wang, Synthesis and structure of a pure inorganic polyoxo-metalate-based porous framework, Chin. Chem. Lett. 23 (2012) 355-358.
4. [4]
  [4] A. Corma, H. García, F.X. LIabré s i Xamena, Engineering metal organic frameworks for heterogeneous catalysis, Chem. Rev. 110 (2010) 4606-4655.
5. [5]
  [5] J.Y. Lee, O.K. Farha, J. Roberts, et al., Metal-organic framework materials as catalysts, Chem. Soc. Rev. 38 (2009) 1450-1459.
6. [6]
  [6] L.Q. Ma, C. Abney, W.B. Lin, Enantioselective catalysis with homochiral metalorganic frameworks, Chem. Soc. Rev. 38 (2009) 1248-1256.
7. [7]
  [7] J.A. Zhao, S.F. Chen, D.D. Zhao, et al., The structure and luminescence properties of three complexes based on bifunctional imidazole-dicarboxylate connector, Chin. Chem. Lett. 24 (2013) 483-486.
8. [8]
  [8] D.B. Shi, Y.W. Ren, H.F. Jiang, J.X. Lu, X.F. Cheng, A new three-dimensional metalorganic framework constructed from 9, 10-anthracene dibenzoate and Cd(Ⅱ) as a highly active heterogeneous catalyst for oxidation of alkylbenzenes, Dalton Trans. 42 (2013) 484-491.
9. [9]
  [9] J.W. Cai, Structural chemistry and properties of metal arenesulfonates, Coord. Chem. Rev. 248 (2004) 1061-1083.
10. [10]
  [10] Z.X. Lian, J.W. Cai, C.H. Chen, H.B. Luo, Linear silver isonicotinamide complex extended by arenedisulfonate via hydrogen bonds and weak Ag. . .O interactions, CrystEngComm 9 (2007) 319-327.
11. [11]
  [11] T.L. Hu, W.P. Du, B.W. Hu, et al., Novel Ag(I) complexes with azole heterocycle ligands bearing acetic acid group: synthesis, characterization and crystal structures, CrystEngComm^-10 (2008) 1037-1043.
12. [12]
  [12] J.P. Zhao, B.W. Hu, F.C. Liu, et al., Arenedisulfonate-lanthanide supramolecular architectures with phenanthroline as a co-ligand: syntheses and structures, CrystEngComm 9 (2007) 902-906.
13. [13]
  [13] C.H. Chen, J.W. Cai, C.Z. Liao, et al., Variation in the coordination mode of arenedisulfonates: syntheses and structural characterization of mononuclear and dinuclear cadmium(Ⅱ) arenedisulfonate complexes with two- to zero-dimensional architectures, Inorg. Chem. 41 (2002) 4967-4974.
14. [14]
  [14] X.Q. Liang, X.H. Zhou, C. Chen, et al., Self-assembly of metal-organic coordination polymers constructed from a versatile multipyridyl ligand: diversity of coordination modes and structures, Cryst. Growth Des. 9 (2009) 1041-1053.
15. [15]
  [15] M.V. Proskumina, N.A. Lozinskaya, S.E. Tkachenko, N.S. Zefirov, Reaction of aromatic aldehydes with ammonium acetate, Russ. J. Org. Chem. 38 (2002) 1149-1153.
16. [16]
  [16] X. Li, B.L. Wu, C.Y. Niu, Y.Y. Niu, H.Y. Zhang, Syntheses of metal-2-(pyridin-4-yl)- 1H-imidazole-4,5-dicarboxylate networks with topological diversity: gas adsorption, thermal stability and fluorescent emission properties, Cryst. Growth Des. 9 (2009) 3423-3431.
17. [17]
  [17] L.E. Martinez, J.L. Leighton, D.H. Carsten, E.N. Jacobsen, Highly enantioselective ring opening of epoxides catalyzed by (salen)Cr(Ⅲ) complexes, J. Am. Chem. Soc. 117 (1995) 5897-5898.
18. [18]
  [18] K. Tanaka, S. Oda, M. Shiro, A novel chiral porous metal-organic framework: asymmetric ring opening reaction of epoxide with amine in the chiral open space, Chem. Commun. 7 (2008) 820-822.
1. [1]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
2. [2]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
3. [3]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
4. [4]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
5. [5]
  Tiantian Li , Ruochen Jin , Bin Wu , Dongming Lan , Yunjian Ma , Yonghua Wang . A novel insight of enhancing the hydrogen peroxide tolerance of unspecific peroxygenase from Daldinia caldariorum based on structure. Chinese Chemical Letters, 2024, 35(4): 108701-. doi: 10.1016/j.cclet.2023.108701
6. [6]
  Xinyi Cao , Yucheng Jin , Hailong Wang , Xu Ding , Xiaolin Liu , Baoqiu Yu , Xiaoning Zhan , Jianzhuang Jiang . A tetraaldehyde-derived porous organic cage and covalent organic frameworks: Syntheses, structures, and iodine vapor capture. Chinese Chemical Letters, 2024, 35(9): 109201-. doi: 10.1016/j.cclet.2023.109201
7. [7]
  Yue Sun , Liming Yang , Yaohang Cheng , Guanghui An , Guangming Li . Pd(I)-catalyzed ring-opening arylation of cyclopropyl-α-aminoamides: Access to α-ketoamide peptidomimetics. Chinese Chemical Letters, 2024, 35(6): 109250-. doi: 10.1016/j.cclet.2023.109250
8. [8]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
9. [9]
  Qinghong Zhang , Qiao Zhao , Xiaodi Wu , Li Wang , Kairui Shen , Yuchen Hua , Cheng Gao , Yu Zhang , Mei Peng , Kai Zhao . Visible-light-induced ring-opening cross-coupling of cycloalcohols with vinylazaarenes and enones via β-C-C scission enabled by proton-coupled electron transfer. Chinese Chemical Letters, 2025, 36(2): 110167-. doi: 10.1016/j.cclet.2024.110167
10. [10]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
11. [11]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
12. [12]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
13. [13]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
14. [14]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
15. [15]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
16. [16]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
17. [17]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
18. [18]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
19. [19]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
20. [20]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(671)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142