Citation: Ming-Xian Liu, Li-Hua Gan, Wei Xiong, Da-Zhang Zhu, Zi-Jie Xu, Long-Wu Chen. Partially graphitic micro- and mesoporous carbon microspheres for supercapacitors[J]. Chinese Chemical Letters, ;2013, 24(12): 1037-1040. shu

Partially graphitic micro- and mesoporous carbon microspheres for supercapacitors

1.
Department of Chemistry, Tongji University, Shanghai 200092, China

Corresponding author: Li-Hua Gan,
Received Date: 31 May 2013
Available Online: 1 July 2013
Fund Project: The project was supported by the National Natural Science Foundation of China (Nos. 21207099, 21273162) (Nos. 21207099, 21273162) Key Subject of Shanghai Municipal Education Commission (No. J50102) (Nos. 11nm0501000, 12ZR1451100)Fundamental Research Funds for the Central Universities (No. 2011KJ023). (No. J50102)

Partially graphitic micro- and mesoporous carbon microspheres (GMMCMs) were synthesized using hydrothermal emulsion polymerization followed by KOH activation and catalytic graphitization. The resulting GMMCMs show micro- and mesopores with a specific surface area of 1113 m²/g, regular spherical shape with diameters of 0.5-1.0 mm and a partially graphitic structure with a low internal resistance of 0.34 Ω. The graphitic carbons as electrode for supercapacitor exhibit a fast ion-transport and rapid charge-discharge feature, and a high-rate electrochemical performance. The typical GMMCM electrode shows a specific capacitance of 220 F/g at 1.0 A/g, and 185 F/g under a high current density of 20.0 A/g in a 6 mol/L KOH electrolyte.
- Micro- and mesoporous carbon,
- microsphere,
- Partially graphitic structure,
- Electrochemical performance,
- Supercapacitor
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沈阳化工大学材料科学与工程学院沈阳 110142