Citation: Liang Ming, Ling Yan Gu, Qing Zhang, Min Zhao Xue, Yan Gang Liu. Preparation and study of photoswitchable fluorescence nanoparticles based on spirobenzopyran[J]. Chinese Chemical Letters, ;2013, 24(11): 1014-1018. shu

Preparation and study of photoswitchable fluorescence nanoparticles based on spirobenzopyran

1.
a School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China;
2.
b School of Pharmacy, Shanghai Jiaotong University, Shanghai 200240, China

Corresponding author: Qing Zhang,
Received Date: 26 March 2013
Available Online: 26 June 2013

The preparation and performance characterization of <50 nm spirobenzopyran-based photochromic nanocomposites with photoswitchable fluorescence are presented. The nanocomposites were fabricated by means of a modified miniemulsion polymerization process, in which the hydrophobic spirobenzopyran was covalently attached to the polymer chains and the matched fluorescent dyes were noncovalently embedded in the nanoscale cross-linked polymeric matrix, respectively. The obtained nanocomposites with a high relative fluorescence quantum yield (Q) exhibited superior fluorescent photoswitchable performance due to the effective photo-induced intermolecular energy transfer. The stability of photomerocyanine was also improved.
- Photoswitchable fluorescence,
- Spirobenzopyrans,
- Miniemulsion polymerization,
- Nanoparticles
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1.
沈阳化工大学材料科学与工程学院沈阳 110142