Citation: Xiu-Li Wang, Jing-Jing Cao, Ji-Lin Hou, Guo-Cheng Liu, Dan Zhao, Xiao-Jing Liu, Na Li, Ai-Xiang Tian. One inorganic-organic hybrid derived from reduced molybdophosphate and trinuclear cadmium(Ⅱ) fragment[J]. Chinese Chemical Letters, ;2013, 24(10): 877-880. shu

One inorganic-organic hybrid derived from reduced molybdophosphate and trinuclear cadmium(Ⅱ) fragment

1.
Department of Chemistry, Bohai University, Liaoning Province Silicon Materials Engineering Technology Research Center, Jinzhou 121000, China

Corresponding author: Xiu-Li Wang,
Received Date: 8 May 2013
Available Online: 31 May 2013
Fund Project: Natural Science Foundation of Liaoning Province (No. 201102003) (No. NCET-09-0853)Program of Innovative Research Team in University of Liaoning Province (No. LT2012020). (No. 201102003)

One new polyoxometalate (POM)-based inorganic-organic hybrid [Cd₃^Ⅱ(HPO₄)(Hbpp)(H₂O)₂]{Cd^Ⅱ[P_4- Mo₆O₂₈H_3.5(OH)₃]₂} (H₄tpb)·7H₂O (1) (bpp = 1,3-bis-(4-pyridyl)propane, tpb = 1,2,4,5-tetra(4-pyridyl)-benzene) constructed from reduced molybdophosphate [P₄Mo₆O₂₈H_3.5(OH)₃]^5.5- (P₄Mo₆), trinuclear Cd^Ⅱ-phosphate-Hbpp fragment and protonated tpb has been hydrothermally synthesized and structurally characterized by IR, elemental analyses and single crystal X-ray diffraction. The complex 1 crystallizes in the monoclinic system with the space group P2₁/c and cell parameters of a = 15.672(12)Å, b = 23.839(19)Å, c = 27.654(2)Å, β = 115.850(10)8, V = 9297.9(12) Å³, Z = 4, R₁ = 0.0534 and wR² = 0.1135. In complex 1, the P₄Mo₆ units are bridged by Cd^Ⅱ ions to form the classic sandwich-type [Cd(P₄Mo₆)₂] dimers, which are further connected into a two dimensional network via the trinuclear Cd^Ⅱ subunits. The tpb is synthesized in situ from the bpp ligands and connects the adjacent 2D layers into a 3D supramolecular framework through hydrogen bonding interactions. The electrochemical and fluorescent properties of complex 1 have been investigated.
- Reduced molybdophosphate,
- Cadmium(Ⅱ) complex,
- In situ synthesis,
- Multi-pyridine ligand
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沈阳化工大学材料科学与工程学院沈阳 110142