Citation: Zhi-Yun Dong, Da-Wei Zhang, Xiao-Zhi Jiang, Hui Li, Guo-Hua Gao. A viologen-urea-based anion receptor： Colorimetric sensing of dicarboxylate anions[J]. Chinese Chemical Letters, ;2013, 24(8): 688-690. shu

A viologen-urea-based anion receptor： Colorimetric sensing of dicarboxylate anions

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a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China;
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b School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Hui Li, Guo-Hua Gao,
Received Date: 22 March 2013
Available Online: 19 April 2013

Compound 1 bearing urea and viologen groups has been designed and synthesized. It could be used as a colorimetric receptor for dicarboxylate anions due to the significant color changes of the solution upon the addition of dicarboxylates. More importantly, the color changes were related to the chain lengths of the dicarboxylates tested. UV-vis, ¹H NMR and HRMS studies demonstrated that receptor 1 utilized hydrogen bonds and electrostatic interactions to form 1:1 stoichiometry complexes with these anions. In addition, the generation of cation radical 1⁺ during the complexation process was also detected by EPR.
- Colorimetric receptor,
- Urea,
- Viologen,
- Dicarboxylate
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沈阳化工大学材料科学与工程学院沈阳 110142