Citation: Ren-Geng Xiong. The temperature-dependent domains, SHG effect and piezoelectric coefficient of TGS[J]. Chinese Chemical Letters, ;2013, 24(8): 681-684. shu

The temperature-dependent domains, SHG effect and piezoelectric coefficient of TGS

Ren-Geng Xiong ^,

1.
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, China

Corresponding author: Ren-Geng Xiong,
Received Date: 28 February 2013
Available Online: 22 April 2013

The temperature-dependent, second-order, nonlinear, optical coefficient (X⁽²⁾), piezoelectric coefficient (d₃₃), pyroelectric coefficient (Ps) and domains on triglycine sulfate (TGS) reported herein provide a clue for us to investigate these as a typical second-order phase transition. The symmetry breaking occurrence is definitely confirmed by the temperature-dependent X⁽²⁾ in which X⁽²⁾ displays a limited value at the ferroelectric phase, indicating the space group (P2₁) chosen is correct, and when X⁽²⁾ basically maintains a zero value at the paraelectric phase, indicating the space group should be centric. Interestingly, after normalization of X⁽²⁾, d₃₃ or Ps, the change trend with temperature is basically overlapped, probably abiding by Landau theory. Moreover, temperature-dependent domains directly show the symmetry breaking occurrence.
- Ferroelectric,
- Piezoelectric force microscopy,
- Symmetry breaking,
- Domains
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