Citation: Bang-Tun Zhao, Xiao-Min Zhu, Xiu-Hua Chen, Zhen-Ning Yan, Wei-Min Zhu. Novel clicked tetrathiafulvalene-calix[4]arene assemblies：Synthesis and intermolecular electron transfer toward p-chloranil[J]. Chinese Chemical Letters, ;2013, 24(07): 573-577. shu

Novel clicked tetrathiafulvalene-calix[4]arene assemblies：Synthesis and intermolecular electron transfer toward p-chloranil

1.
a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China;
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b College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Bang-Tun Zhao, Wei-Min Zhu,
Received Date: 8 February 2013
Available Online: 19 March 2013

Two tetrathiafulvalene-calix[4]arene assemblies (TTF-calix-1 and TTF-calix-2) have been synthesized by the click reaction. Both their cyclic voltammograms show, as expected, two one-electron quasi-reversible redox behavior. The UV-vis absorption spectra studies show that these two assemblies undergo progressive oxidation at the TTF moiety in presence of increasing amounts of Cu²⁺ or Hg²⁺. Moreover, the absorption studies show intermolecular electron transfer between compounds TTF-calix-1 or TTF-calix-2 and p-chloranil may be promoted by specific metal ions such as Pb²⁺, Sc³⁺ etc.
- Tetrathiafulvalene,
- Calix[4]arene,
- Click reaction,
- Chloranil,
- Intermolecular electron transfer
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沈阳化工大学材料科学与工程学院沈阳 110142