Citation: Lan Yu, Qi Wang, Lu Dai, Wei-Ying Li, Rong Chen, Mian HR Mahmood, Hai-Yang Liu, Chi-Kwong Chang. Solvent effects on oxygen atom transfer reaction between manganese(V)-oxo corrole and alkene[J]. Chinese Chemical Letters, ;2013, 24(6): 447-449. shu

Solvent effects on oxygen atom transfer reaction between manganese(V)-oxo corrole and alkene

Lan Yu ^a ,
Qi Wang ^a ,
Lu Dai ^a ,
Wei-Ying Li ^a ,
Rong Chen ^a ,
Mian HR Mahmood ^a ,
Hai-Yang Liu ^a,, ,
Chi-Kwong Chang ^b,,

1.
a Department of Chemistry, South China University of Technology, Guangzhou 510640, China;
b Department of Chemistry, Michigan State University, E.
b Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA

Corresponding author: Hai-Yang Liu, Chi-Kwong Chang,
Received Date: 16 January 2013
Available Online: 3 March 2013

-first order reaction rate constants of 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo (F₅CMn(V)-oxo), 5,15-bis(pentafluorophenyl)-10-(phenyl)corrole Mn(V)-oxo (F₁₀CMn(V)-oxo), 5,15-bis(phenyl)-10-(pentafluorophenyl)corrole Mn(V)-oxo (F₅CMn(V)-oxo) and 5,10,15-tris(phenyl)corrole Mn(V)-oxo (F₀CMn(V)-oxo) with a series of alkene substrates in different solvents were determined by UV-vis spectroscopy. The results indicated that the oxygen atom transfer pathway between Mn(V)-oxo corrole and alkene is solvent-dependent.
- Corrole,
- Mn(V)-oxo corrole,
- Oxygen atom transfer reaction,
- Solvent effect
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