Citation: Sadegh Rostamnia, Fatemeh Pourhassan. The SBA-15/SO₃H nanoreactor as a highly efficient and reusable catalyst for diketene-based, four-component synthesis of polyhydroquinolines and dihydropyridines under neat conditions[J]. Chinese Chemical Letters, ;2013, 24(05): 401-403. shu

The SBA-15/SO₃H nanoreactor as a highly efficient and reusable catalyst for diketene-based, four-component synthesis of polyhydroquinolines and dihydropyridines under neat conditions

Sadegh Rostamnia ^, ,
Fatemeh Pourhassan

1.
Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, P. O. Box 55181-83111, Maragheh, Iran

Corresponding author: Sadegh Rostamnia,
Received Date: 4 January 2013
Available Online: 28 February 2013

An efficient diketene ring-opening synthesis of polyhydroquinoline derivatives using SBA-15 sulfonic acid modified mesoporous substrates a green and reusable catalyst in a single-pot four-component coupling reaction of diketene, alcohol, enamine, and aldehydes is reported. Dihydropyridine derivatives based on neat adduct of diketene, alcohols and aldehydes using SBA-15/SO₃H nanoreactor as catalyst via a four-component reactions are also synthesized. The advantages of the present method include the use of a small amount catalyst, simple procedure with an easy filterable work-up, waste-free, green and direct synthetic method with an excellent yield of products with efficient use of catalyst and a short reaction time.
- SBA-15/SO₃H,
- Nanoreactor,
- Diketene,
- Polyhydroquinoline
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沈阳化工大学材料科学与工程学院沈阳 110142

The SBA-15/SO3H nanoreactor as a highly efficient and reusable catalyst for diketene-based, four-component synthesis of polyhydroquinolines and dihydropyridines under neat conditions

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通讯作者: 陈斌, bchen63@163.com

The SBA-15/SO₃H nanoreactor as a highly efficient and reusable catalyst for diketene-based, four-component synthesis of polyhydroquinolines and dihydropyridines under neat conditions