Citation: Fei Gao, Jian-Bin Zhang, Chun-Ping Li, Tian-Rui Huo, Xiong-Hui Wei. Supramolecular binding of amines with functional magnesium tetraphenylporphyrin for CO₂ capture[J]. Chinese Chemical Letters, ;2013, 24(3): 249-252. shu

Supramolecular binding of amines with functional magnesium tetraphenylporphyrin for CO₂ capture

1.
a College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, China;
2.
b Department of Applied Chemistry, College of Chemistry & Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: Jian-Bin Zhang, Xiong-Hui Wei,
Received Date: 8 November 2012
Available Online: 2 January 2013

In this work,magnesium tetraphenylporphyrin (MgTPP) was used as a new supramolecular amine-fixing agent. Once introduced, CO₂ easily competes with MgTPP for amines, leading to the release of MgTPP. The processes can be explained by the fact that the association constant (K_assoc) values of MgTPP with amines were in the range of 0.6 (ethanolamine) to 3.9 (ethylenediamine), which are lower than the K_assoc values of CO₂ with these amines. MgTPP interacted with aniline, ethanolamine, pyrrolidine, or ethylenediamine to form 1:1 adducts. Ethylenediamine presents a stronger K_assoc value for MgTPP, so it was considered an optimal agent for CO₂ capture.
- Supramolecular binding,
- Fixation,
- Amine,
- Magnesium tetraphenylporphyrin,
- CO₂ capture
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Supramolecular binding of amines with functional magnesium tetraphenylporphyrin for CO2 capture

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通讯作者: 陈斌, bchen63@163.com

Supramolecular binding of amines with functional magnesium tetraphenylporphyrin for CO₂ capture