Citation: Chun-Hua Ge, Rui Zhang, Ping Fan, Xiang-Dong Zhang, Li-Juan Wang, Fang-Fang Wang. Supramolecular assembly of 2,4,5-trifluorobenzoate complex based on weak interactions involving fluorine atoms[J]. Chinese Chemical Letters, ;2013, 24(01): 73-75. shu

Supramolecular assembly of 2,4,5-trifluorobenzoate complex based on weak interactions involving fluorine atoms

1.
College of Chemistry, Liaoning University, Shenyang 110036, China

Corresponding author: Xiang-Dong Zhang,
Received Date: 30 August 2012
Available Online: 19 November 2012

The complex[Cd(tfbz)₂(phen)]₂(1)(tfbz=2,4,5-trifluorobenzoate,phen=1,10-phenanthro-line)was synthesized using trifluorobenzoic acid ligand.The single-crystal structure of 1 has been determined by X-ray crystallography.The packing structure is characterized by the formation of an intricate three-dimensional supramolecular network that depends on the C-H…F,F…F,F(lp)…π(lp=lone pair) interactions.
- 2,4,5-Trifluorobenzoate,
- Crystal structure,
- Weak interaction
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1.
沈阳化工大学材料科学与工程学院沈阳 110142