Citation: Hua Xiang, Long Jiang, Huan-Yong Li, Xiao-Dan Zheng, Yu Li. Synthesis and characterization of a tetranuclear copper(Ⅱ) complex with a chiral Schiff base ligand[J]. Chinese Chemical Letters, ;2013, 24(01): 49-51. shu

Synthesis and characterization of a tetranuclear copper(Ⅱ) complex with a chiral Schiff base ligand

Hua Xiang ^a,, ,
Long Jiang ^b ,
Huan-Yong Li ^b ,
Xiao-Dan Zheng ^b ,
Yu Li ^c,,

1.
a Department of Media and Communication, Guangdong Industry Technical College, Guangzhou 510300, China;
2.
b School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China;
3.
c Department of Chemical Engineering, Guangdong Industry Technical College, Guangzhou 510300, China

Corresponding author: Hua Xiang, Yu Li,
Received Date: 12 September 2012
Available Online: 8 November 2012

The title complex l-[Cu₄^Ⅱ(Hvap)₂(vap)₂(MeOH)₂](ClO₄)₂ 1 has been synthesized and characterized by EA, IR,TGA,solid-state CD spectra and X-ray single-crystal analyses(l-H₂vap:a Schiff base ligand derived from the condensation of o-vanillin and l-2-amino-3-phenyl-1-propanol).Complex 1 crystallizes in monoclinic system,chiral space group P2₁ with a=10.4257(18),b=21.695(4),c=15.721(3)Å β=94.443(3)°,V=3545.1(11)Å³,Z=2,Cu₄C₇₀H₇₈N₄O₂₂C_l2,Mr=1652.42,D_c=1.548 g/cm³, F(0 0 0)=1704 and μ(MoKα)=1.338 mm^-1.The final R=0.0682 and wR=0.1420 for 6170 observed reflections with I2δ(I)and R=0.1775 and wR=0.1830 for all data.The structure of complex 1 contains a boat-shaped{Cu₄O₄}motif.The solid-state CD spectra confirm the chiral nature of complex 1.
- Chiral polynuclear complex,
- Copper(Ⅱ)complex,
- Crystal structure,
- CD spectra
1. [1]
  [1] Y.Sui,D.P.Li,C.H.Li,et al.,Ionic ferroelectrics based on nickel Schiff base complexes,Inorg.Chem.49(2010)1286-1288.
2. [2]
  [2] C.F.Wang,Z.G.Gu,X.M.Lu,et al.,Ferroelectric heterobimetallic clusters with ferromagnetic interactions,Inorg.Chem.47(2008)7957-7959.
3. [3]
  [3] J.F.Zhang,S.Meng,Y.L.Song,et al.,Facile syntheses and tunable non-linear optical properties of heterothiometallic clusters with[MS₄Ag₂] units(M=Mo,W),Chem. Eur.J.16(2010)13946-13950.
4. [4]
  [4] G.J.Cao,W.H.Fang,S.T.Zheng,et al.,(CH₃NH₃)₂[Ge(B₄O₉)] :an organically-templated chiral borogermanate with second-order nonlinear and ferroelectric properties,Inorg.Chem.Commun.13(2010)1047-1049.
5. [5]
  [5] C.Jahier,M.F.Coustou,M.Cantuel,et al.,Optically active tripodal dendritic polyoxometalates:synthesis,characterization and their use in asymmetric sulfide oxidation with hydrogen peroxide,Eur.J.Inorg.Chem.(2011)727-738.
6. [6]
  [6] E.S.Andreiadis,M.R.Vitale,N.Mézailles,et al.,Chiral undecagold clusters: synthesis,characterization and investigation in catalysis,Dalton Trans.39 (2010)10608-10616.
7. [7]
  [7] H.Horáková,B.Grüner,R.Vespalec,Emerging subject for chiral separation science:cluster boron compounds,Chirality 23(2011)307-319.
8. [8]
  [8] M.Paluch,K.Ślepokura,T.Lis,et al.,Enantiopure trinuclear lanthanide(Ⅲ) complexes:cooperative formation of Ln3(m3-OH)2 core within the macrocycle, Inorg.Chem.Commun.14(2011)92-95.
9. [9]
  [9] C.Train,M.Gruselle,M.Verdaguer,The fruitful introduction of chirality and control of absolute configurations in molecular magnets,Chem.Soc.Rev.40 (2011)3297-3312.
10. [10]
  [10] M.Andruh,Compartmental Schiff-base ligands-a rich library of tections in designing magnetic and luminescent materials,Chem.Commun.47(2011)3025-3042.
11. [11]
  [11] J.K.Tang,I.Hewitt,N.T.Madhu,et al.,Dysprosium triangles showing single-molecule magnet behavior of thermally excited spin states,Angew.Chem.Int.Ed. 45(2006)1729-1733.
12. [12]
  [12] G.M.Sheldrick,SADABS,Program for Empirical Absorption Correction of Area Detector Data,University of Göttingen,Göttingen,1996.
13. [13]
  [13] G.M.Sheldrick,SHELXS 97,Program for Crystal Structure Refinement,University of Göttingen,Göttingen,1997.
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