Citation: Hamid Tajizadegan, Mehdi Rashidzadeh, Majid Jafari, Reza Ebrahimi-Kahrizsangi. Novel ZnO-Al2O3 composite particles as sorbent for low temperature H2S removal[J]. Chinese Chemical Letters, ;2013, 24(2): 167-169. shu

Novel ZnO-Al2O3 composite particles as sorbent for low temperature H2S removal

  • Corresponding author: Hamid Tajizadegan, 
  • Received Date: 28 September 2012
    Available Online: 24 December 2012

  • ZnO-Al2O3 composite particles composed of ZnO nanosheets (thickness of 40-80 nm) on alumina particles were prepared by heterogeneous precipitation method using bayerite seed particles. The asprepared composite particles were characterized in terms of crystal structure,morphology, surface area and pore volume. The composite particles were used as sorbent for H2S adsorption at low temperature, and were compared with pure ZnO sorbent. The composite sorbent showed a greater sulfur adsorption capacity (0.052 g/g) than pure form of ZnO (0.028 g/g). This significant improvement was mainly attributed to higher surface area, more pore volume and unique morphology in nanoscale, which were also obtained by low cost presented method in this work for synthesis of ZnO sorbent supported on alumina particles.
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    1. [1]

      [1] D. Stirling, The Sulfur Problem: Cleaning up Industrial Feedstocks, The Royal Society of Chemistry, Cambridge, 2000.

    2. [2]

      [2] C. Li, Z.S. Yu, S.M. Fang, et al., Fabrication and gas sensing property of honeycomblike ZnO, Chin. Chem. Lett. 19 (2008) 599-603.

    3. [3]

      [3] J. Skrzypski, I. Bezverkhyy, O. Heintz, J.P. Bellat, Low temperature H2S removal with metal-doped nanostructure ZnO sorbents: study of the origin of enhanced reactivity in Cu-containing materials, Ind. Eng. Chem. Res. 50 (2011) 5714-5722.

    4. [4]

      [4] I. Rosso, C. Galletti, M. Bizzi, G. Saracco, V. Specchia, Zinc oxide sorbents for the removal of hydrogen sulfide from syngas, Ind. Eng. Chem. Res. 42 (2003) 1688-1697.

    5. [5]

      [5] Y.J. Lee, N.K. Park, G.B. Han, et al., The preparation and desulfurization of nano-size ZnO by a matrix-assisted method for the removal of low concentration of sulfur compounds, Curr. Appl. Phys. 8 (2008) 746-751.

    6. [6]

      [6] T.J. Lee, I.H. Cho, N.K. Park, Desulfurization using ZnO nanostructure prepared by matrix assisted method, Korean J. Chem. Eng. 26 (2009) 582-586.

    7. [7]

      [7] R. Habibia, A.M. Rashidib, J.T. Daryana, A.M. Ali Zadeh, Study of the rod-like and spherical nano-ZnO morphology on H2S removal from natural gas, Appl. Surf. Sci. 257 (2010) 434-439.

    8. [8]

      [8] I.I. Novochinskii, C.H. Song, X. Ma, et al., Low temperature H2S removal from steam-containing gas mixtures with ZnO for fuel cell application: 1. ZnO particles and extrudates, Energy Fuels 18 (2004) 576-583.

    9. [9]

      [9] G. Liua, Z.H. Huanga, F. Kang, Preparation of ZnO/SiO2 gel composites and their performance of H2S removal at room temperature, J. Hazard. Mater. 215-216 (2012) 166-172.

    10. [10]

      [10] X. Wang, T. Sun, J. Yang, L. Zhao, J. Jia, Low-temperature H2S removal from gas streams with SBA-15 supported ZnO nanoparticles, Chem. Eng. J. 142 (2008) 48-55.

    11. [11]

      [11] L. Chen, J. Shen, Effect of resorcinol formaldehyde resin gel on the preparation of Co/SiO2 catalysts for Fischer-Tropsch synthesis, Chin. J. Catal. 33 (2012) 621-628.

    12. [12]

      [12] Qiherima, H. Li, H. Yuan, Y. Zhang, G. Xu, Effect of alumina support on the formation of the active phase of selective hydrodesulfurization catalysts Co-Mo/Al2O3, Chin. J. Catal. 32 (2011) 240-249.

    13. [13]

      [13] Qiherima, H. Yuan, H.F. Li, Y.H. Zhang, G.T. Xu, Investigation on the active phase of Co/Mo catalyst for selective HDS by low temperature in situ FT-IR, Chin. Chem. Lett. 22 (2011) 366-369.

    14. [14]

      [14] K. Wefers, C. Misra, Oxides and Hydroxides of Aluminum, Alcoa Research Laboratories, Pennsylvania, 1987.

    15. [15]

      [15] C. Xu, J. Sun, B. Zhao, Q. Liu, On the study of KF/Zn(Al)O catalyst for biodiesel production from vegetable oil, Appl. Catal. B 99 (2010) 111-117.

    16. [16]

      [16] M. Mozibur Rahman, M.K.R. Khan, M. Rafiqul Islam, et al., Effect of Al doping on structural, electrical, optical and photoluminescence properties of nano-structural ZnO thin films, J. Mater. Sci. Technol. 28 (2012) 329-335.

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