Citation: Xue Yi LE, Fu Hai WU, Fen Yun SONG, Liang Nian JI. THE STACKING INERACTION OF TERNARY COMPLEXES OF Zn(ATP)^2- AND PYRIDINE-LIKELIGANDS[J]. Chinese Chemical Letters, ;1995, 6(9): 801-804. shu

THE STACKING INERACTION OF TERNARY COMPLEXES OF Zn(ATP)^2- AND PYRIDINE-LIKELIGANDS

Xue Yi LE ^a,b ,
Fu Hai WU ^a,b ,
Fen Yun SONG ^a,b ,
Liang Nian JI ^a,b

a Departmetn of Chemistry, Zhongshan University, Guangzhou 510275;
b The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210008

Received Date: 18 January 1995

Fund Project: This work was supported by the Doctoral Program Foundation of Institution of High Education, and National Natural Science Foundation of P. R. China.

The stability constants of ternary complexes of the type Zn(ATP)L^2-, where L=pyridine, 4-picoline, 3, 4-lutidine and 3, 5-lutidine, have been determined by potentiometric pH titration in aqueous solution and compared with the stability of the corresponding binary complexes ZnL²⁺.It has been observed that there is a stacking interaction between the pyridine ring of the pyridine-like ligands and the purine moiety of ATP in the ternary Zn(ATP)L^2- complexes and this stacking interaction is stronger than that in corresponding Co (ATP) L^2- complexes.
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