Citation: Shu Xia LIU, Chun Mei WANG, Hong Ju ZHAI, De Hui LI, En Bo WANG. Synthesis and Crystal Structures of Novel Keggin and Dawson Polyoxometalates Containing Amantadine[J]. Chinese Chemical Letters, ;2004, 15(2): 216-219. shu

Synthesis and Crystal Structures of Novel Keggin and Dawson Polyoxometalates Containing Amantadine

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024

Received Date: 6 January 2003

Fund Project: Financial Support from NNSFC is gratefully acknowledged (Granted:20071008).

Two novel polyoxometalates containing pharmaceutical component amantadine, formulated with (C₁₀H₁₈N)₅PMo₁₂O₄₀Cl₂·5H₂O (I) and (C₁₀H₁₈N)₆As₂Mo₁₈O₆₂·6CH₃CN·6H₂O(II) were first synthesized and characterized by IR, UV-Vis spectra and X-ray diffraction. Structural analyses of I and II suggested that polyanions in these compounds were reserved their Keggin or Dawson structures and were linked to amantadine through electrostatic interaction and hydrogen bonding.
- Amantadine,
- polyoxometalate,
- synthesis,
- crystal structure
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