Citation: Xu Dong LIU, Meng Xian DING, Lian Xun GAO. Synthesis and Catalytic Application of Chiral 1, 1'-Binaphthyl Polymers[J]. Chinese Chemical Letters, ;2004, 15(1): 32-34. shu

Synthesis and Catalytic Application of Chiral 1, 1'-Binaphthyl Polymers

State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 2 January 2003

The synthesis of a new type of polymers with main chain chirality based on BINOL skeleton is described. Titanium-BINOLate catalysts are easily generated from these polymers and applied to the asymmetric reaction of Et₂Zn with benzaldehyde. The products are obtained in good yields with moderate enantioselectivities.
- Asymmetric catalysis,
- chiral polymers,
- BINOL
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