Citation: Zhi Feng FU, Yan SHI, Ming Zhi HUANG, Shu Ke JIAO. Atom Transfer Radical Polymerization of Methyl Methacrylate with α,α-Dichlorotoluene or α,α,α-Trichlorotoluene as Initiator[J]. Chinese Chemical Letters, ;1999, 10(7): 611-614. shu

Atom Transfer Radical Polymerization of Methyl Methacrylate with α,α-Dichlorotoluene or α,α,α-Trichlorotoluene as Initiator

Department of Polymer Science, Beijing University of Chemical Technology, Beijing 100029

Received Date: 7 December 1998

The atom transfer radical polymerization (ATRP) of methyl methacrylate using α.α-dichlorotoluene or α.α,α-trichlorotoluene as the initiator and CuCl/2,2'-bipyridine complex as the catalyst was investigated. α,α-Dichlorotoluene gave good control of molecular weight with high initiation etliciency and low polydispersity. While α,α,α-trichlorotoluene gave very slow polymerization rate. which could be improved by the addition of Cu (0) to the system.
- atom transfer radical polymerization(ATRP),
- methyl methacrylate,
- initiator
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