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Citation: CHANG HUNG-TSE, CHAD VE-HSIAO, VOONG SING-TUH. STUDIES ON THE REACTION MECHANISM OF CYCLOPOLYMERIZATION[J]. Acta Polymerica Sinica, ;1964, 6(1): 61-70. shu

STUDIES ON THE REACTION MECHANISM OF CYCLOPOLYMERIZATION

Through kinetic method, the reaction mechanism of cyclopolymerization of 1,1-diallyl-diethylmalonate (DDM) and diallyl-phthalate (DAP) has been studied. Besides mono-molecular mechanism of ordinary inter-intramolecular polymerization consideration, we proposed the linear equation of cyclopolymerization through consideration of both mono-molecular and bimolecular reaction mechanism. It was found that this linear equation could be applied successfully not only to the above two cases but also to the cyclopoly-merization data from Aso.
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