Citation: Matthias Scharfe, Guido Zichittella, Vladimir Paunović, Javier Pérez-Ramírez. Ceria in halogen chemistry[J]. Chinese Journal of Catalysis, ;2020, 41(6): 915-927. doi: S1872-2067(19)63528-X shu

Ceria in halogen chemistry

Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, 8093 Zurich, Switzerland

Received Date: 14 September 2019
Revised Date: 18 October 2019

Fund Project: This work was supported by the ETH Research Grant ETH-04 16-1.

Halogen chemistry constitutes an essential part in the industrial production of polymers and gains increasing attention as an attractive strategy to activate light alkanes that constitute natural gas. CeO₂-based catalysts offer an exciting potential for advances in hydrogen halide recovery that enables a high efficiency of halogen-based processes for activation of small molecules. This review provides an overview of recently developed ceria-based catalysts in the context of polymer industry (polyvinyl chloride, polyurethanes, and polycarbonates) and activation of light hydrocarbons for natural gas upgrading. In addition, mechanistic insight and the challenges of ceria catalysts are provided, aiding the design of future catalytic materials and applications
- CeO₂,
- Hydrogen halides,
- Ethylene,
- Alkanes,
- Selective natural gas upgrading,
- Oxidation,
- Oxyhalogenation,
- Vinyl chloride
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