Citation: Gan Yu, Xinqing Chen, Wenjie Xue, Lixia Ge, Ting Wang, Minghuang Qiu, Wei Wei, Peng Gao, Yuhan Sun. Melting-assisted solvent-free synthesis of SAPO-11 for improving the hydroisomerization performance of n-dodecane[J]. Chinese Journal of Catalysis, ;2020, 41(4): 622-630. doi: S1872-2067(19)63466-2 shu

Melting-assisted solvent-free synthesis of SAPO-11 for improving the hydroisomerization performance of n-dodecane

Gan Yu ^a,b,c, ,
Xinqing Chen ^b,c ,
Wenjie Xue ^b ,
Lixia Ge ^b ,
Ting Wang ^b ,
Minghuang Qiu ^b ,
Wei Wei ^a,b ,
Peng Gao ^b ,
Yuhan Sun ^a,b

a School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China;
b CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China;
c University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 30 September 2019
Revised Date: 27 October 2019

Fund Project: This work was supported by the National Natural Science Foundation of China (21776295) and the Youth Innovation Promotion Association, CAS (2017355).

A novel melting-assisted solvent-free route using solid oxalic acid was proposed for the post-treatment of SAPO-11 zeolite, followed by loading with 0.5 wt% Pt by the incipient wetness impregnation method. Subsequently, the performance of the obtained bifunctional catalysts toward the hydroisomerization of n-dodecane was examined. The prepared samples were characterized by XRD, SEM, BET, XRF, Py-IR, and solid-state NMR. From the results, it was found that the high crystallinity and uniform morphology were retained after the post-treatment and that more (002) crystal faces were exposed, which was beneficial since more acid sites were provided. More importantly, the total Brönsted acid sites and the ratio (R_a) of the micropore area to the total surface area were optimized by this method. Thus, the catalytic performance was enhanced significantly, and the prepared Pt-SAPO-11-10% catalyst had the highest i-dodecane yield of 80.1% compared to 55.3% of Pt-SAPO-11. Expectedly, this facile and cost-effective method is promising for the hydroisomerization of normal paraffin in the production of lubricant base oils.
- Hydroisomerization,
- Zeolite,
- SAPO-11,
- Melting-assist,
- Bifunctional catalyst,
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
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